@article {48374, title = {Concurrent polyvalent interaction and electrocatalysis to improve lithium-sulfur battery performance}, journal = {Batteries \& Supercaps}, volume = {5}, year = {2022}, month = {FEB}, type = {Article}, abstract = {

Batteries with improved efficiency are desired. Li-S batteries are attractive due to their high specific capacity and energy density. However, sluggish sulfur redox reaction and polysulfide dissolution are significant challenges in Li-S batteries. In this work, we report graphene with doped layer to electrocatalyze the sluggish sulfur redox reaction. The doped layer comprises heteroatoms such as either N or N and S. The doped layer also comprises cations of Ni. We have chosen a {\textquoteleft}{\textquoteleft}doped layer on graphene{\textquoteright}{\textquoteright} over {\textquoteleft}{\textquoteleft}doped graphene{\textquoteright}{\textquoteright} to avoid defects in the basal plane of graphene. We found the doped layer comprising graphene (DLC-G) to electrocatalyze the polysulfide redox reaction. However, the interaction between the doped layer and polysulfide is still weak, hence the dissolution is not suppressed. To circumvent the polysulfide dissolution, graphene with cationic layer was prepared. We found that cations in the layer electrostatically attract the polysulfides due to the polyvalent interaction. Thus, the dissolution is suppressed. While using this material in the Li-S batteries, the specific capacity, energy density and power density were found to be 1345 mAh g(-1), 782 Wh kg(-1) and 4437 W kg(-1), respectively.

}, keywords = {electrocatalysis, graphene, lithium-sulfur battery, mechanical exfoliation, polyvalent interaction}, doi = {10.1002/batt.202100229}, author = {Kumar, Subramani and Krishnamoorthy, Kothandam} } @article {49590, title = {Heteroatom-synergistic effect on anchoring polysulfides in chalcone-linked nanographene covalent organic frameworks for high-performance Li--S batteries}, journal = {Advanced Science}, volume = {12}, year = {2025}, month = {APR}, type = {Article}, abstract = {

Lithium-sulfur (Li \& horbar;S) batteries are an attractive option for future energy storage devices because they offer higher theoretical specific capacity, energy density, and cost-effectiveness than commercial lithium-ion batteries. However, the practical applications of Li \& horbar;S batteries are significantly limited by the shuttle effect caused by intermediate lithium polysulfides (LiPSs) and slow redox kinetics. In this study, the molecular engineering of chalcone-linked, sp(2)-bonded nanographene-type covalent organic frameworks (COFs) as sulfur hosts is reported to enhance interactions with LiPSs, thereby effectively suppressing the shuttle effect. The developed sulfur-hosting cathode material demonstrated outstanding battery performance, surpassing most reported materials by achieving a specific capacity of 1228 mA h g(-1) at 0.5C, with 80\% retention after 500 cycles and an average Coulombic Efficiency (C.E.) of 99\%. Additionally, the mechanisms of sulfur immobilization, the subsequent conversion into lithium polysulfides (LiPSs), and their binding energies with COFs are investigated using density functional theory (DFT) calculations. These findings offer valuable insights into the structure-property relationships essential for developing more efficient sulfur-hosting cathodes.

}, keywords = {anion-pi interaction, covalent organic frameworks, lithium-sulfur battery, nanographene, polysulfide shuttle}, doi = {10.1002/advs.202415897}, author = {Ranjeesh, Kayaramkodath Chandran and Javaregowda, Bharathkumar H. and Gaber, Safa and Bhauriyal, Preeti and Kumar, Sushil and Skorjanc, Tina and Finsgar, Matjaz and Heine, Thomas and Krishnamoorthy, Kothandam and Shetty, Dinesh} } @article {49618, title = {Methoxyl-containing hyper-crosslinked polymer from largely bio-based biphenyl methyl ether and its application in lithium-sulfur battery}, journal = {Reactive \& Functional Polymers}, volume = {207}, year = {2025}, month = {FEB}, pages = {106139}, type = {Article}, abstract = {

A new biphenyl methyl ether viz 2,2 {\textquoteleft},3,3 {\textquoteleft}-tetramethoxy-5,5 {\textquoteleft}-bis(methoxymethyl)-1,1 {\textquoteleft}-biphenyl (TBMB) was synthesized starting from vanillin via three-step reaction sequence. The self-polycondensation of TBMB by employing two Bronsted acid catalysts, viz, p- toluenesulfonic acid (PTSA) and trifluoromethanesulfonic acid (TFSA) led to the formation of organic hyper-crosslinked polymers (HCPs) containing built-in methoxyl groups. HCPs were characterized by FTIR, solid state 13 C NMR, XPS, XRD, TGA, BET, and FESEM analysis techniques. HCPs synthesized using PTSA (HCP-PTSA) and TFSA (HCP-TFSA) exhibited a Brunauer-Emmett-Teller (BET) surface area of 480 +/- 5 and 590 +/- 4 m2/g, respectively and consisted of hierarchical pore structures with both micropores and mesopores. HCP-TFSA was evaluated as an active coating layer on conventional polypropylene (PP) separator in lithium-sulfur batteries to suppress the polysulfide shuttling on account of the ability of methoxyl groups to anchor soluble polysulfide species via coordination. The significant polysulfide adsorption capacity and improved cycling stability with a capacity of 617.2 mAh g- 1 at 0.5C and 99\% capacity retention highlighted the potential of porous HCP containing built-in methoxyl groups in the development of attractive lithium-sulfur battery systems.

}, keywords = {Active coating layer, bio-based, Biphenyl methyl ether, Hyper-crosslinked polymer, lithium-sulfur battery, Methoxyl groups, Self-polycondensation}, issn = {1381-5148}, doi = {10.1016/j.reactfunctpolym.2024.106139}, author = {Wale, Apparav K. and Das, Anoushka K. and Patil, Nita R. and Shelke, V. Manjusha and Ambade, V. Ashootosh and Wadgaonkar, Prakash P.} }