@article { ISI:000228940600001,
	title = {Short S=O center dot center dot center dot C=O contacts associate diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate in their inclusion complexes},
	journal = {Crystal Growth \& Design},
	volume = {5},
	number = {3},
	year = {2005},
	month = {MAY},
	pages = {833-836},
	publisher = {AMER CHEMICAL SOC},
	type = {Article},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>Diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate are linked via short S=O\&amp;BULL;\&amp;BULL;\&amp;BULL; C=O contacts ranging from 2.890 to 3.140 \&amp;ANGS; (sum of the van der Waals radii of O and C atoms 3.22 \&amp;ANGS;) in all the inclusion complexes formed with organic guest solvents having a C2 symmetry. Although a search for S= O\&amp;BULL;\&amp;BULL;\&amp;BULL; C=O interactions in the CSD showed a sizable number of structures, this communication recognizes its significance for the first time in the formation of molecular assemblies. In all the crystals in the present study except the solvent-free form, the S=O bond points almost perpendicularly to the Csp2 atom of the C=O group. This was also the most frequently observed geometrical approach in CSD analysis. The solvent-free form shows dimer formation via C-H\&amp;BULL;\&amp;BULL;\&amp;BULL; O interaction, which has longer S=O\&amp;BULL;\&amp;BULL;\&amp;BULL; C=O contacts.</p>},
	issn = {1528-7483},
	doi = {10.1021/cg049621k},
	author = {Manoj, Kochunnoonny and Sureshan, K. M. and Gonnade, Rajesh G. and Bhadbhade, Mohan M. and Shashidhar, M. S.}
}
@article { ISI:000228607400011,
	title = {Sulfonate protecting groups. synthesis of O- and C-methylated inositols: D- and L-ononitol, D- and L-laminitol, mytilitol and scyllo-inositol methyl ether},
	journal = {Tetrahedron},
	volume = {61},
	number = {18},
	year = {2005},
	month = {MAY},
	pages = {4437-4446},
	publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
	type = {Article},
	address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
	abstract = {<p>Syntheses of D- and L-ononitol, D- and L-laminitol, mytilitol and scyllo-inositol methyl ether starting from myo-imositol are described. One or two of the inyo-inositol 1,3,5-orthoformate hydroxyl groups were protected as tosylates. These mono or ditosylates served as key intermediates for the preparation of O- and C-methyl inositols. Racemic 2,4-di-O-tosyl-myo-inositol 1,3,5-orthoformate was resolved as its diastereomeric camphanates. Use of sulfonate groups for the protection of inositol hydroxyl groups resulted in substantial improvement in the overall yield of O- and C-methyl inositols. (c) 2005 Elsevier Ltd. All rights reserved.</p>},
	keywords = {Cyclitol, Inositol, Orthoester, Protecting group, sulfonate},
	issn = {0040-4020},
	doi = {10.1016/j.tet.2005.02.073},
	author = {Sarmah, M. P. and Shashidhar, M. S. and Sureshan, K. M. and Gonnade, Rajesh G. and Bhadbhade, Mohan M.}
}
