@article {42817,
	title = {Steric control in pd-mediated cycloisomerization of sugar alkynols: documentation of a rare allylic epimerization},
	journal = {Tetrahedron Letters},
	volume = {48},
	year = {2007},
	month = {JUL},
	pages = {4771-4774},
	type = {Article},
	abstract = {<p>Pd-mediated cycloisomerization of C3-alkynylated glucofuranosyl derivatives revealed a dominance of steric factors over electronic factors. However, the intermediate glycals were epimerized prior to the ketalization and afforded the more stable cis-fused bicyclic ketals. (c) 2007 Elsevier Ltd. All rights reserved.</p>},
	keywords = {Bis-Homopropargylic Alcohols; Oriented Organic-Synthesis;Nucleophilic-Attack; Room-Temperature; Palladium; Chemistry; Heterocycles;Complexes; Transformations; Sonogashira},
	doi = {10.1016/j.tetlet.2007.04.133},
	author = {Ramana, Chepuri V. and Patel, Pitarnbar and Gonnade, Rajesh G.}
}
