@article { ISI:000255774700006,
	title = {Rigid bicyclo[3.3.0]octane (octahydropentalene): a heavily constrained novel aliphatic template for molecular self-assembly},
	journal = {Tetrahedron Letters},
	volume = {49},
	number = {19},
	year = {2008},
	month = {MAY},
	pages = {3056-3059},
	publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
	address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
	abstract = {<p>This Letter reports the utility of a heavily constrained cis-fused bicyclo[3.3.0]octane (octahydropentalene) aliphatic template for effecting molecular self-assembly. An attractive feature of this system is its heavily constrained alicyclic backbone that would allow for the exploration of self-assembling systems with conformationally ordered features. (C) 2008 Elsevier Ltd. All rights reserved.</p>},
	issn = {0040-4039},
	doi = {10.1016/j.tetlet.2008.03.062},
	author = {Kendhale, Amol M. and Gonnade, Rajesh G. and Rajamohanan, P. R. and Sanjayan, Gangadhar J.}
}
@article { ISI:000364933100004,
	title = {Reversed reactivity of anilines with alkynes in the rhodium-catalysed C-H activation/carbonylation tandem},
	journal = {Nature Communications},
	volume = {6},
	year = {2015},
	month = {OCT},
	pages = {Article Number: 8591},
	publisher = {NATURE PUBLISHING GROUP},
	address = {MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND},
	abstract = {<p>Development of multicatalytic approach consisting of two or more mechanistically distinct catalytic steps using a single-site catalyst for rapid and straightforward access of structurally complex molecules under eco-benign conditions has significance in contemporary science. We have developed herein a rhodium-catalysed C-H activation strategy which uses an unprotected anilines and an electron-deficient alkynes to C-C bonded products as a potential intermediate in contrast to the archetypical C-N bonded products with high levels of regioselectivity. This is followed by carbonylation of C-H bond activated intermediate and subsequent annulation into quinolines has been described. This rhodium-catalysed auto-tandem reaction operates under mild, environmentally benign conditions using water as the solvent and CO surrogates as the carbonyl source with the concomitant generation of hydrogen gas. The strategy may facilitate the development of new synthetic protocols for the efficient and sustainable production of chemicals in an atom-economic way from simple, abundant starting materials.</p>},
	issn = {2041-1723},
	doi = {10.1038/ncomms9591},
	author = {Midya, Siba Prasad and Sahoo, Manoj Kumar and Landge, Vinod Gokulkrishna and Rajamohanan, P. R. and Balaraman, Ekambaram}
}
