@article { ISI:000378303400056,
	title = {Nucleophilic nitration of arynes by sodium nitrite and its multicomponent reaction leading to double-functionalized arenes},
	journal = {Organic Letters},
	volume = {18},
	number = {12},
	year = {2016},
	month = {JUN},
	pages = {3010-3013},
	publisher = {AMER CHEMICAL SOC},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>An unusual nucleophilic nitration of arynes by NaNO2 in the presence of water has been developed, and the concept was further demonstrated to accomplish a double functionalization of arynes using a multicomponent reaction protocol to synthesize pharmaceutically important (2-nitrophenyl)methanol derivatives. Such substitution ortho to -NO2 is difficult by other means. The reaction conditions are mild and avoid the use of strong acids, expensive transition metal catalysts, and additives.</p>},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.6b01384},
	author = {Dhokale, Ranjeet A. and Mhaske, Santosh B.}
}
@article {43683,
	title = {Diversity-oriented synthesis of spiroannulated benzofuran-3-one scaffold of leptosphaerin C and congeners via aryne insertion},
	journal = {Journal of Organic Chemistry},
	volume = {82},
	year = {2017},
	month = {MAY},
	pages = {4875-4882},
	type = {Article},
	abstract = {A concise synthesis of functionalized cyclohexenone-fused spirobenzofuran-3-ones under mild reaction conditions was developed. The reaction proceeds via insertion of aryne into the C-O bond followed by a regioselective intramolecular conjugate addition. The use of silyl-protected acid was crucial for the transformation. This protocol was successfully applied for the synthesis of leptosphaerin C core and its novel analogues.},
	doi = {10.1021/acs.joc.7b00606},
	author = {Dhokale, Ranjeet A. and Mhaske, Santosh B.}
}
@article {44238,
	title = {Transition-metal-catalyzed reactions involving arynes},
	journal = {Synthesis-Stuttgart},
	volume = {50},
	year = {2018},
	month = {JAN},
	pages = {1-16},
	type = {Article},
	abstract = {<p>The plethora of transformations attainable by the transition-metal-catalyzed reactions of arynes has found immense contemporary interest in the scientific community. This review highlights the scope and importance of transition-metal-catalyzed aryne reactions in the field of synthetic organic chemistry reported to date. It covers transformations achieved by the combination of arynes and various transition metals, which provide a facile access to a biaryl motif, fused polycyclic aromatic compounds, different novel carbocycles, various heterocycles, and complex natural products. 1 Introduction 2 Insertion of Arynes 3 Annulation of Arynes 4 Cycloaddition of Arynes 5 Multicomponent Reactions of Arynes 6 Miscellaneous Reactions of Arynes 7 Total Synthesis of Natural Products Using Arynes 8 Conclusion</p>},
	keywords = {annulation, arynes, Cycloaddition, Insertion, multicomponent, Natural products, Transition Metal},
	issn = {0039-7881},
	doi = {10.1055/s-0036-1589517},
	author = {Dhokale, Ranjeet A. and Mhaske, Santosh B.}
}
