@article { ISI:000318001400027,
	title = {Diverted total syntheses of potent cell adhesion inhibitor peribysin E analogues},
	journal = {Organic Letters},
	volume = {15},
	number = {8},
	year = {2013},
	month = {APR},
	pages = {1894-1897},
	publisher = {AMER CHEMICAL SOC},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>Preliminary results from a program aimed at the creation of a focused library of analogues around the natural product peribysin E, a potent biologically active and structurally fascinating molecule, are reported. The total synthesis of (+/-)-peribysin E was accomplished using a short route. Eight new analogues of the natural compound have been accomplished by means of {\textquoteleft}{\textquoteleft}diverted total synthesis{\textquoteright}{\textquoteright} in less than 10 steps. The present effort highlights protecting-group-free total syntheses and the shortest route to access these functionally embellished hydrindanes.</p>},
	issn = {1523-7060},
	doi = {10.1021/ol400555m},
	author = {Handore, Kishor L. and Reddy, D. Srinivasa}
}
@article {49799,
	title = {Diastereoselective synthesis of cyclic and spirocyclic quaternary carbons via iron-catalyzed ring contraction of cyclic ketones: a formal synthesis of perhydrohistrionicotoxin},
	journal = {Organic Letters},
	volume = {27},
	year = {2025},
	month = {AUG },
	pages = {8798-8803},
	type = {Article},
	abstract = {<p>
	The iron-catalyzed hydrogen atom transfer (HAT)-initiated Dowd-Beckwith rearrangement presents a new approach for synthesizing cyclic and spirocyclic quaternary carbons from readily available beta-keto esters and cyclic diketones with high yields. This reaction proceeds in a stereocontrolled manner, enabling the formation of synthetically valuable cyclic ketones with two contiguous stereocenters, including quaternary centers. This transformation introduces an innovative bond disconnection strategy for ring-contraction reactions. Additionally, a short formal synthesis of perhydrohistrionicotoxin was efficiently achieved using this methodology.</p>
},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.5c02888},
	author = {Survase, Vijayanand U. and Rokade, Avinash D. and Handore, Kishor L.}
}
