@article { ISI:000365445500001,
	title = {Water-promoted diels-alder reaction in quaternary ammonium salts},
	journal = {Journal of Physical Organic Chemistry},
	volume = {28},
	number = {11},
	year = {2015},
	month = {NOV},
	pages = {665-673},
	publisher = {WILEY-BLACKWELL},
	address = {111 RIVER ST, HOBOKEN 07030-5774, NJ USA},
	abstract = {<p>{Prevailing classification of salts based on their effect in solubility and stability of proteins in aqueous solution predicts that tetraalkylammonium salts, guanidinium chloride (GnCl), LiClO4 act as salting-in (S/I) and LiCl, NaCl act as salting-out (S/O) in aqueous conditions. In the same context the behaviour of GnCl, LiClO4 and LiCl are contradictory in polar solvents like ethylene glycol and formamide. In these solvents, expected salt effect shows just opposite nature from their usual expectation. However, in the aqueous solution salts like tetraalkylammonium halide (R4NX</p>},
	keywords = {Delta G(solvation), Diels-Alder reaction, k(s), kinetic study, solubility, tetraalkylammonium salts, viscosity},
	issn = {0894-3230},
	doi = {10.1002/poc.3469},
	author = {Nagare, Amit S. and Manna, Arpan and Sonawane, Pramod D. and Kumar, Anil}
}
@article { ISI:000381182700004,
	title = {Spectacular rate enhancement of the diels-alder reaction at the ionic liquid/n-hexane interface},
	journal = {Chemphyschem},
	volume = {17},
	number = {13},
	year = {2016},
	month = {JUL},
	pages = {1969-1972},
	publisher = {WILEY-V C H VERLAG GMBH},
	address = {POSTFACH 101161, 69451 WEINHEIM, GERMANY},
	abstract = {<p>The use of the ionic liquid/n-hexane interface as a new class of reaction medium for the Diels-Alder reaction gives large rate enhancements of the order of 10(6) to 10(8) times and high stereoselectivity, as compared to homogeneous media. The rate enhancement is attributed to the H-bonding abilities and polarities of the ionic liquids, whereas the hydrophobicity of ionic liquids was considered to be the factor in controlling stereoselectivity.</p>},
	keywords = {Diels-Alder reaction, Interfaces, ionic liquids, kinetics, stereoselectivity},
	issn = {1439-4235},
	doi = {10.1002/cphc.201600006},
	author = {Beniwal, Vijay and Manna, Arpan and Kumar, Anil}
}
