@article { ISI:000248062700019,
	title = {Exhaustive analysis of frontal copolymerization of functionalized monovinyl and divinyl monomers},
	journal = {Chemistry-A European Journal},
	volume = {13},
	number = {20},
	year = {2007},
	month = {APR},
	pages = {5862-5872},
	publisher = {WILEY-V C H VERLAG GMBH},
	type = {Article},
	address = {BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY},
	abstract = {<p>A series of copolymers of 2-hydroxyethyl methacrylate (HEMA)/ glycidyl methacrylate (GMA) and ethylene dimethacrylate (EGDM) were synthesized by frontal polymerization (FP). This study was conducted to investigate the effect of crosslink density, type and concentration of initiator, the use of a complex initiator system, porogen, and diluent on the most relevant parameters of FP, such as sustainability of the front, temperature profile, front velocity, and yield. The products were also characterized for intruded pore volume, pore-size distribution, epoxy-functionality number, and surface morphology. Higher crosslink densities (CLDs) and initiator concentration produced higher front velocities, whereas no trend in front temperature was noted. A complex initiation system was effective in stabilizing and increasing the polymerization yield. Relative to suspension polymerization (SP), FP products synthesized without a solvent were microporous, whereas micro-to-macroporous products were obtained in the presence of a solvent (for HEMA-EGDM polymers). We also present, explain, and discuss the exotic patterns observed under a microscope. We observed two basic types of spatial patterns, namely, planar and nonplanar patterns. The type of planar pattern observed under scanning electron microscopy (SEM) has a spatial impulse that appears as a loop followed by regular periodic motion in the radial and axial directions. This behavior gives rise to a repeating pattern that is a few microns thick. Also, nonplanar patterns, namely, layered concentric rings and winding staircase patterns, were observed under SEM.</p>},
	keywords = {copolymerization, patterns, Polymers, porosity},
	issn = {0947-6539},
	doi = {10.1002/chem.200601428},
	author = {Pujari, Narahari S. and Inamdar, Satish R. and Ambekar, Jalindar D. and Kulkarni, B. D. and Ponrathnam, Surendra}
}
@article { ISI:000379253100009,
	title = {Synthesis of 2-phenoxy-2-phenylethyl acrylate and copolymerization with 2-phenylethyl acrylate: estimation of monomer reactivity ratios, thermal and optical properties},
	journal = {Journal of Macromolecular Science Part A-Pure and Applied Chemistry},
	volume = {53},
	number = {7},
	year = {2016},
	month = {MAY},
	pages = {457-464},
	publisher = {TAYLOR \& FRANCIS INC},
	address = {530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 USA},
	abstract = {<p>A new aromatic based monomer 2-phenoxy-2-phenylethyl acrylate (PPEA) was synthesized. Copolymers of PPEA with 2-phenylethyl acrylate (PEA) were prepared by free radical polymerization. The reactivity ratios were estimated using various graphical methods. Structural parameters of the copolymers were obtained by calculating the dyad monomer sequence fractions and the mean sequence length. Optical properties of polymers such as refractive indices and UV-Visible absorption were investigated. The glass transition temperature and thermal degradation behavior of the copolymers were studied. Combined with the RI, transparency and thermal properties, prepared copolymers hold great promise as materials for intraocular lens applications.</p>},
	keywords = {2-Phenoxy-2-phenylethyl acrylate, 2-phenylethyl acrylate, copolymerization, Optical properties, reactivity ratios, Thermal properties},
	issn = {1060-1325},
	doi = {10.1080/10601325.2016.1176447},
	author = {Ghorpade, Ravindra V. and Ponrathnam, Surendra and Chavan, Nayaku}
}
