@article { ISI:000263365600013,
	title = {NC palladacycles in the Heck arylation of ethylene: synthesis, structure and their reactivity},
	journal = {Journal of Organometallic Chemistry},
	volume = {694},
	number = {5},
	year = {2009},
	month = {MAR},
	pages = {683-690},
	publisher = {ELSEVIER SCIENCE SA},
	address = {PO BOX 564, 1001 LAUSANNE, SWITZERLAND},
	abstract = {<p>Monomeric cyclopalladated complexes with NC coordination using ligands 2-phenylpyridine, 2-phenylquinoline, 8-methylquinoline have been synthesized and the structures have been determined by single crystal X-ray structure analysis. The crystal structures of monomeric palladacycles prepared using benzophenone oxime, and 2-phenylpyridine have also been determined. The use of these complexes in the Heck arylation of ethylene with 2-bromo-6-methoxynaphthalne (BMN) to give 2-vinyl-6-methoxynapthalene which is an intermediate for the synthesis of anti-inflammatory drug Naproxen has been examined and also arylation of ethylene with 3-bromo-benzophenone and 4-bromo-isobutylbenzene was investigated. These palladacycles with NC coordination show excellent catalytic activity with a TOF \&gt; 4000 h (1). (C) 2008 Elsevier B.V. All rights reserved.</p>},
	keywords = {alpha-Aryl propionic acids, Arylation, Palladacycle},
	issn = {0022-328X},
	doi = {10.1016/j.jorganchem.2008.11.065},
	author = {Atla, Shashi B. and Kelkar, Ashutosh A. and Puranik, Vedavati G. and Bensch, Wolfgang and Chaudhari, Raghunath V.}
}
