@article {48723,
	title = {Pd nanoparticles supported on N-incorporated hybrid organosilica as an active and selective low-temperature phenol hydrogenation catalyst},
	journal = {ACS Applied Nano Materials},
	volume = {6},
	year = {2023},
	month = {JUN},
	pages = {11500-11512},
	type = {Article},
	abstract = {<p>
	A heterogeneous Pd-NPMO hybrid-silicacatalyst is synthesized andits application for aqueous phase selective hydrogenation of phenolto cyclohexanone at near ambient temperature (40 degrees C) and underatmospheric hydrogen pressure is demonstrated. The homogeneously distributedPd nanoparticles on N-bridged hybrid mesoporous organosilica showedremarkable activity and selectivity for cyclohexanone compared tothe unmodified Pd-SBA-15 catalyst. Control experiments strongly claimthe role of nitrogen domains in the organic framework of hybrid silicasupport in stabilizing small Pd nanoparticles and possibly modifyingthe Pd sites responsible for catalysis to activate the substrate moleculesin water. The hybrid silica catalyst was stable and reused severaltimes without any significant drop-in activity, proving the heterogeneityof the bifunctional Pd catalyst. Based on the density functional theorystudy and experimental interventions, a possible reaction mechanismfor the low-temperature phenol hydrogenation explaining the role oforganic domains in the hybrid-silica framework is proposed.</p>
},
	keywords = {cyclohexanone, Hybrid silica, palladium nanoparticles, Periodic mesoporous organosilica, phenol hydrogenation},
	doi = {10.1021/acsanm.3c01540},
	author = {Betsy, K. J. and Bajpai, Priyam and Lazar, Anish and Vanka, Kumar and Vinod, C. P.}
}
