@article { ISI:000261133600029,
	title = {New microporous MOF material based on Zn(II)-polycarboxylate coordination polymer synthesized with the aid of 1,6-diaminohexane as template},
	journal = {Microporous and Mesoporous Materials},
	volume = {116},
	number = {1-3},
	year = {2008},
	month = {DEC},
	pages = {204-209},
	publisher = {ELSEVIER SCIENCE BV},
	type = {Article},
	address = {PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS},
	abstract = {<p>A new microporous metal-organic framework (MOF) material ZBTEC-1 has been synthesized by designing infinite coordination polymer network formed between Zn(II) and 1,2,4,5-benzenetetracarboxylic acid (BTEC) under solvothermal conditions in the presence of 1,6-diaminohexane (DAH) as a single molecule template. Powder XRD data demonstrate that the ZBTEC-1 material has a new MOF structure. N-2 sorption studies indicated moderately good surface area (306 m(2) g(-1)) with large size micropores (average pore diameter ca. 0.7 nm) and very high pore volume (1.93 ccg(-1)). C-13 solid state MAS-NMR, FT-IR and UV-visible spectroscopic studies showed the presence of BTEC moieties in the framework. TEM and FE-SEM analysis indicated 30-60 nm diameter size microporous spherical particles for the ZBTEC-1 crystallites. This novel MOF material showed good hydrogen adsorption capacity at 77 K, indicating its potential application in hydrogen storage. (C) 2008 Elsevier Inc. All rights reserved.</p>},
	keywords = {Coordination polymer, Metal-organic framework, Microporous material, porosity, Zinc complex},
	issn = {1387-1811},
	doi = {10.1016/j.micromeso.2008.04.003},
	author = {Chandra, Debraj and Kasture, Mahesh W. and Bhaumik, Asim}
}
