@article { ISI:000253382100048,
	title = {PdCl2(bipy) complex - an efficient catalyst for Heck reaction in glycol-organic biphasic medium},
	journal = {Catalysis Today},
	volume = {131},
	number = {1-4},
	year = {2008},
	note = {4th Asia-Pacific Congress on Catalysis, Nanyang Technol Univ, Singapore, SINGAPORE, DEC 06-08, 2006},
	month = {FEB},
	pages = {353-359},
	publisher = {ELSEVIER SCIENCE BV},
	address = {PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS},
	abstract = {<p>The Palladium complex PdCl2(bipy) (1) was found to be efficient in catalyzing the Heck reaction of aryl halides in a biphasic system comprising ethylene glycol along with an organic solvent. A proper tailoring of the organic phase ensured that the leaching of the catalyst to the organic phase was negligible. The catalyst was active for the Heck reaction of a number of olefins, aryl halides, in presence of organic and inorganic bases. The PdCl2(bipy) catalyst was stable and could be recycled for five times without any loss in activity and selectivity. A major advantage of this work is that unlike hitherto reported biphasic systems; it does not employ a water-soluble ligand to achieve biphasic catalysis. (c) 2007 Elsevier B.V. All rights reserved.</p>},
	keywords = {Biphasic catalysis, C-C coupling, Heck reaction, PdCl2(bipy) complex},
	issn = {0920-5861},
	doi = {10.1016/j.cattod.2007.10.043},
	author = {Jagtap, Sangeeta Vijay and Deshpande, Raj Madhukar}
}
@article { ISI:000318393000043,
	title = {True water soluble palladium-catalyzed Heck reactions in aqueous-organic biphasic media},
	journal = {Tetrahedron Letters},
	volume = {54},
	number = {21},
	year = {2013},
	month = {MAY},
	pages = {2733-2736},
	publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
	address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
	abstract = {<p>A stable water soluble palladium catalyst has been demonstrated for the Heck reaction in a biphasic medium (water-non-polar organic solvent). Biphasic Heck reactions reported till now generally employ a non-polar solvent along with an aqueous polar water miscible organic solvent as the second phase. The efficiency of the Pd complex of TOTPS [Trisodium salt of tri-(ortho-tolyl) phosphine tri sulfonate] for the vinylation of different aryl iodides and olefins is demonstrated. The advantages of a co-solvent for this biphasic system have also been shown. The catalyst has been recycled efficiently retaining the activity with negligible loss of catalyst and without leaching of the Pd. (c) 2013 Elsevier Ltd. All rights reserved.</p>},
	keywords = {Aqueous biphasic catalysis, C-C coupling, Heck reaction, Water-soluble catalyst},
	issn = {0040-4039},
	doi = {10.1016/j.tetlet.2013.03.067},
	author = {Jagtap, Sangeeta Vijay and Deshpande, Raj Madhukar}
}
