@article { ISI:000325642400017, title = {Electrophile induced branching cascade: a powerful approach to access various molecular scaffolds and their exploration as novel anti-mycobacterial agents}, journal = {Chemical Communications}, volume = {49}, number = {86}, year = {2013}, month = {SEP}, pages = {10109-10111}, publisher = {ROYAL SOC CHEMISTRY}, address = {THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND}, abstract = {

Herein we report on the Electrophile Induced Branching Cascade (EIBC), a new technique to produce a variety of biologically important molecular scaffolds. Some compounds exhibit excellent activities against Mycobacterium smegmatis.

}, issn = {1359-7345}, doi = {10.1039/c3cc45289a}, author = {Patil, Nitin T. and Konala, Ashok and Sravanti, Sudha and Singh, Ashita and Ummanni, Ramesh and Sridhar, Balasubramanian} } @article {42863, title = {Relay catalytic branching cascade: technique to access diverse molecular scaffolds}, journal = {Angewandte Chemie International Edition}, volume = {52}, year = {2013}, month = {JAN}, pages = {2251-2255}, doi = {10.1002/anie.201208738}, author = {Patil, Nitin T. and Shinde, Valmik S. and Sridhar, Balasubramanian} } @article {46952, title = {Catalyst-free regioselective [3+2] cycloadditions of alpha,beta-unsaturated N-arylnitrones with alkenes to access functionalized isoxazolidines: a DFT study}, journal = {Chemistry-An Asian Journal}, volume = {15}, year = {2020}, month = {MAR}, pages = {899-903}, type = {Article}, abstract = {

The catalyst-free regioselective [3+2]-cycloaddition of alpha,beta-unsaturated N-arylnitrones with alkenes are developed. The series of synthetically important functionalized isoxazolidines are prepared in good to excellent yields by step economic pathway under ligand and transition-metal-free conditions. The regioselective cycloaddition pathway supported by control experiment and computational study.

}, keywords = {DFT study, isoxazolidines, metal and ligand free, nitrone cycloaddition, Regioselective}, issn = {1861-4728}, doi = {10.1002/asia.201901754, Early Access Date = FEB 2020}, author = {Ghosh, Arnab and Mane, Manoj V. and Rode, Haridas B. and Patil, Siddappa A. and Sridhar, Balasubramanian and Dateer, Ramesh B.} } @article {49082, title = {Total synthesis and revision of stereochemistry of a natural benzo[g]isochromene stereodiad isolated from rubia philippinensis}, journal = {Organic Letters}, volume = {26}, year = {2024}, month = {MAR }, pages = {2574-2579}, type = {Article}, abstract = {

This study presents a total synthesis and revision of the stereochemical configuration of the conformationally flexible natural product benzo[g]isochromene stereodiad alongside its diastereomeric counterparts. The highlights of the synthesis are the TiCl4-mediated diastereoselective aldol reaction, Pd-catalyzed lactonization, and Schmidt glycosidation. Our efforts using total synthesis disclosed herein proved that a previously assigned structure required revision.

}, issn = {1523-7060}, doi = {10.1021/acs.orglett.4c00553}, author = {Choudhury, Rahul and Miriyala, Satya Ravi Teja and Resmi, K. R. and Sridhar, Balasubramanian and Kasa, S. R. Krishna Murthy and Reddy, D. Srinivasa} }