@article { ISI:000368563000067,
	title = {Pt- and TCO-free flexible cathode for DSSC from highly conducting and flexible PEDOT paper prepared via in situ interfacial polymerization},
	journal = {ACS Applied Materials \& Interfaces},
	volume = {8},
	number = {1},
	year = {2016},
	month = {JAN},
	pages = {553-562},
	publisher = {AMER CHEMICAL SOC},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>Here, we report the preparation of a flexible, free-standing, Pt- and TCO-free counter electrode in dye-sensitized solar cell (DSSC)-derived from polyethylenedioxythiophene (PEDOT)-impregnated cellulose paper. The synthetic strategy of making the thin flexible PEDOT paper is simple and scalable, which can be achieved via in situ polymerization all through a roll coating technique. The very low sheet resistance (4 Omega/square) obtained from a film of 40 mu m thick PEDOT paper (PEDOT-p-5) is found to be superior to the conventional fluorine-doped tin oxide (FTO) substrate. The high conductivity (357 S/cm) displayed by PEDOT-p-5 is observed to be stable under ambient conditions as well as flexible and bending conditions. With all of these features in place, we could develop an efficient Pt- and TCO-free flexible counter electrode from PEDOT-p-5 for DSSC applications. The catalytic activity toward the tri-iodide reduction of the flexible electrode is analyzed by adopting various electrochemical methodologies. PEDOT-p-5 is found to display higher exchange current density (7.12 mA/cm(2)) and low charge transfer resistance (4.6 Omega) compared to the benchmark Pt-coated FTO glass (2.40 mA/cm(2) and 9.4 Omega, respectively). Further, a DSSC fabricated using PEDOT-p-5 as the counter electrode displays a comparable efficiency of 6.1\% relative to 6.9\% delivered by a system based on Pt/FTO as the counter electrode.</p>},
	keywords = {counter electrode, dye-sensitized solar cell, flexible and thin devices, impedance analysis, interfacial polymerization, polyethylenedioxythiophene},
	issn = {1944-8244},
	doi = {10.1021/acsami.5b09579},
	author = {Anothumakkool, Bihag and Agrawal, Ishita and Bhange, Siddheshwar N. and Soni, Roby and Game, Onkar S. and Ogale, Satishchandra B. and Kurungot, Sreekumar}
}
@article {42969,
	title = {Phenothiazine-based D-A-π-A dyes for highly efficient dye sensitized solar cells: effect of internal acceptor and non-conjugated π-spacer on device performance},
	journal = {ChemPlusChem},
	volume = {82},
	year = {2017},
	month = {FEB},
	pages = {280-286},
	abstract = {Three new D-A-pi-A metal-free organic dyes based on phenothiazine as a donor (D) and non-conjugated pi-spacer were designed and synthesized. The incorporation of different {\textquoteright}internal acceptors{\textquoteright} (electron traps) such as benzothiadiazole (BTD), benzotriazole (BTA), and pyridine were shown to allow systematic tuning of the energy levels and the photophysical properties. The AI-1 dye showed lower electronic disorder compared with the other two dyes. The efficiencies achieved with AI-1, AI-2, and AI-3 dyes were 8.5\% (J(sc) = 15.42 mA cm(-2), V-oc = 0.78 V, FF = 68\%), 7\% (J(sc) = 12.8 mA cm(-2), V-oc = 0.78 V, FF = 68\%) and 6.7\% (J(sc) = 11.57 mA cm(-2), V-oc = 0.82 V, FF = 68.26 \%), respectively. The incorporation of non-conjugated phenothiazine as a p-spacer in D-A-pi-A dyes showed remarkable enhancement in the photovoltaic performance of dye-sensitized solar cell (DSSC) devices. The sealed DSSC devices with iodide/tri-iodide (I-/I-3(-) @)based liquid electrolyte showed promising stability under ambient conditions.},
	doi = {10.1002/cplu.201600492},
	author = {Nagane, Satyawan and Ichake, Amol and Agrawal, Ishita and Sadhanala, Aditya and Friend, Richard H. and Ogale, Satishchandra and Wadgaonkar, Prakash P.}
}
