@article { ISI:000256839100021,
	title = {Stereoselective synthesis of beta-C-Allyl- and beta-C-propargyl-D-arabinofuranosides},
	journal = {Synthesis-Stuttgart},
	number = {11},
	year = {2008},
	month = {JUN},
	pages = {1783-1787},
	publisher = {GEORG THIEME VERLAG KG},
	address = {RUDIGERSTR 14, D-70469 STUTTGART, GERMANY},
	abstract = {<p>The stereoselective synthesis of beta-configured C-allyl- and C-propargyl-D-arabinofuranosides (4,7-anhydro-1,2,3-deoxy-D-gluco-oct-1-enitols and -oct-1-ynitols) was addressed by employing allylation/propargylation of a dialdofuranose under aqueous Barbier reaction conditions and acid-catalyzed furan ring transposition of 5-O-mesyl-manno-oct-7-eno- or 5-O-mesyl-manno-oct-7-ynofuranoside derivatives.</p>},
	keywords = {Allylation, Barbier reaction, C-glycoside, D-mannose, propargylation, Ring transposition},
	issn = {0039-7881},
	doi = {10.1055/s-2008-1067016},
	author = {Ramana, C. V. and Narute, Sachin B. and Gonnade, Rajesh G. and Patil, Rahul S.}
}
@article {42807,
	title = {Synthesis of C(27){\textendash}C(38) fragment of aflastatin A},
	journal = {Tetrahedron},
	volume = {69},
	year = {2013},
	month = {JAN},
	pages = {1830{\textendash}1840},
	abstract = {<p>Efforts at finding out a strategy for the synthesis of the densely hydroxylated C(27){\textendash}C(48) fragment of aflastatin A have been described. The initial studies dealing with alkyne{\textendash}epoxide coupling using a linear polyol epoxide resulted in a debenzylative cycloetherification leading to a C-arabinoside derivative. This problem has been addressed by applying an epoxide pendant on a furanosyl unit. With the model alkyne, the epoxide{\textendash}alkyne coupling proceeded smoothly. Subsequently, following a sequence of [Pd]-mediated alkynone cycloisomerization/stereoselective hydroboration{\textendash}oxidation, the synthesis of the central C(27){\textendash}C(38) fragment has been executed. When employed, the original C(33){\textendash}C(48) alkyne, the coupling and the cycloisomerizations are facile. However, the resulting glycals are unstable, thus warranting a revision in our approach.</p>},
	keywords = {Aflastatin; Epoxide{\textendash}alkyne coupling; ω-Alkynone cycloisomerization; Palladium catalysis; Hydroboration},
	doi = {10.1016/j.tet.2012.12.065},
	author = {Narute, Sachin B. and Ramana, C.V.}
}
@article { ISI:000326290300011,
	title = {Synthesis of C-disaccharides through a one-pot alkynol cycloisomerization-reductive deoxygenation},
	journal = {Chemistry-A European Journal},
	volume = {19},
	number = {45},
	year = {2013},
	month = {NOV},
	pages = {15109-15114},
	publisher = {WILEY-V C H VERLAG GMBH},
	address = {BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY},
	keywords = {C-disaccharides, carbohydrates, Epoxide-alkyne coupling, Gold catalysis, Reductive deoxygenation},
	issn = {0947-6539},
	doi = {10.1002/chem.201302252},
	author = {Narute, Sachin B. and Rout, Jeetendra Kumar and Ramana, Chepuri V.}
}
