@article {49982, title = {Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-amino-benzoxazole}, journal = {Acta Crystallographica Section E, Crystallographic Communications}, volume = {81}, year = {2025}, month = {JUN}, pages = {482-485}, type = {Article}, abstract = {

A coordination complex of cadmium nitrate [Cd(NO3)2] with 2-amino-benzaxole (2AB; C7H6N2O), namely, tetra-kis-(2-amino-benzoxazole-κN1)bis-(nitrato-κO)cadmium(II), [Cd(NO3)2(2AB)4], has been synthesized from ethanol solutions of Cd(NO3)2{\textperiodcentered}H2O and 2AB. The asymmetric unit comprises half a mol-ecule of [Cd(NO3)2(2AB)4], with the CdII\ atom positioned on a twofold rotation axis. In the completed mol-ecular complex, four 2AB ligands and two nitrate anions each coordinate monodentately to the CdII\ atom, leading to a distorted octa-hedral coordination environment. The crystal structure of [Cd(NO3)2(2AB)4] exhibits several N-H...O inter-actions, resulting in the formation of a layered assembly parallel to (001). Hishfeld surface analysis was used to qu-antify the inter-molecular inter-actions.

}, doi = {10.1107/S2056989025004049}, author = {Razzoqova, Surayyo and Ruzimov, Yodgor and Toshov, Akobir and Torambetov, Batirbay and Ibragimov, Aziz and Ashurov, Jamshid and Kadirova, Shakhnoza} }