@article {49829,
	title = {Total synthesis of isatisindigoticanine H},
	journal = {Synthesis-Stuttgart},
	volume = {57},
	year = {2025},
	month = {SEP},
	pages = {2677-2682},
	type = {Article},
	abstract = {<p>
	The first total synthesis of the naturally occurring isatisindigoticanine H has been completed by employing D-mannitol as the chiral pool precursor to install the requisite stereochemistry of the natural product. Construction of the thiazole unit by dehydrative cyclization of a alpha-halo ketone with thiourea followed by Sandmeyer{\textquoteright}s reaction and subsequent nucleophilic addition of lithiated bromothiazole to the Weinreb amide are the key reactions employed in this regard.</p>
},
	keywords = {Chiral pool approach, Indothiazinone, Isatisindigoticanine H, Sandmeyer reaction, Total synthesis},
	issn = {0039-7881},
	doi = {10.1055/a-2618-0514},
	author = {Wabale, Krishna R. and Ramana, Chepuri Venkata}
}
@article {50105,
	title = {Total synthesis of triplinone F},
	journal = {Journal of Organic Chemistry},
	volume = {91},
	year = {2026},
	month = {APR },
	pages = {5694-5698},
	type = {Article},
	abstract = {<p>
	The first total synthesis of triplinone F, along with its C11 epimer, has been executed to establish, inter alia, the stereochemistry of C11 and its complete absolute configuration. The terminal styrene unit was added by cross-metathesis, whereby 1,3-diol units on either side of the central olefin were taken from malic acid enantiomers and coupled by a Yamaguchi alkyne-epoxide opening protocol. The C11 stereochemistry was manipulated by Noyori asymmetric ynone reduction. The Z-selective reduction of alkynoate and acid-catalyzed lactonization forged the right-hand-side 5,6-dihydro-delta-pyrone unit.</p>
},
	issn = {0022-3263},
	doi = {10.1021/acs.joc.5c03126},
	author = {Shet, Manoj N. and Wabale, Krishna R. and Ramana, Chepuri V.}
}
