@article {49704,
	title = {Manganese(<sc>i</sc>)-catalyzed dehydrogenative borylation of terminal alkynes},
	journal = {Dalton Transactions},
	volume = {54},
	year = {2025},
	month = {JUL},
	pages = {10426-10432},
	type = {Article},
	abstract = {<p>
	Compounds containing carbon-boron bonds serve as valuable intermediates for constructing more complex molecules by transforming these bonds into other carbon-element bonds. The catalytic dehydrogenative borylation of carbon-hydrogen bonds using HBpin presents an appealing method for synthesizing carbon-boron bonds. While this approach has been extensively explored with noble metals for various types of carbon-hydrogen bonds, its application with manganese-based catalysts remains rare. This study explores a dehydrogenative borylation process employing an Earth-abundant transition metal catalyst, FcbpyMn(CO)3Br (Mn(i)), in combination with HBpin under mild conditions. Arylalkynes featuring electron-withdrawing, electron-donating, and heteroaryl substituents yielded good to excellent results. Thorough DFT calculations were performed to understand the mechanism.</p>
},
	issn = {1477-9226},
	doi = {10.1039/d5dt00577a},
	author = {Ghanwat, Pratiksha B. and Bora, Debashree and Pandya, Rinu and Vanka, Kumar and Saha, Biswajit and Sen, Sakya S.}
}
