@article {49567,
	title = {Separation of isomers of chiral thiourea derivatives via spontaneous resolution and rationale of molecular recognition},
	journal = {CrystEngComm},
	volume = {27},
	year = {2025},
	month = {FEB},
	pages = {1240-1247},
	type = {Article},
	abstract = {<p>
	Enrichment of enantiomers during crystallization of racemic thiourea derivatives was investigated. The spontaneous resolution of a chiral thiourea derivative via preferential crystallization is attributed to thermodynamic stability when molecules of identical chirality bind with each other in the crystal lattice. Single crystal X-ray analysis reveals the interactions responsible for self-recognition of molecules of the same chirality in the unit cell. The tendency of the thiourea derivative to form a conglomerate is supported by IR spectroscopy, thermal analysis and computational studies.</p>
},
	doi = {10.1039/d4ce01226g},
	author = {Dwivedi, Astha M. and Gonnade, Rajesh G. and Sahoo, Suban K. and Bedekar, Ashutosh V.}
}
