@article { ISI:000248203200019,
	title = {Synthesis and evaluation of 1-deoxy-8-epi-castanospermine, 1-deoxy-8-hydroxymethyl castanospermine, and (6S,7S,8R,8aR)-8-amino-octahydroindolizine-6,7-diol},
	journal = {Tetrahedron},
	volume = {63},
	number = {22},
	year = {2007},
	month = {MAY},
	pages = {4756-4761},
	publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
	type = {Article},
	address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
	abstract = {<p>A short, versatile, and enantioselective synthesis of 1-deoxy-8-epi-castanospermine (5), 1-deoxy-8-hydroxymethyl castanospermine (6), and (6S,7S,8R,8aR)-8-amino-octahydroindolizine-6,7-diol (7) is achieved from a common template 12. The key step utilized is PET provoked amine radical cyclization of 11 to 12 in excellent diastereoselectivity. The exocyclic double bond at C-8 of the template is functionalized to obtain 5-7 as exclusive diastereomers. 1-Deoxy-8-epi-castanospermine exhibited inhibition of alpha- and beta-galactosidase and beta-glucosidase. Compounds 6 and 7 were found to be weak inhibitors of beta-glucosidase. (C) 2007 Elsevier Ltd. All rights reserved.</p>},
	keywords = {1-deoxy-8-epi-castanospermine, castanospermine, Glycosidase inhibitors},
	issn = {0040-4020},
	doi = {10.1016/j.tet.2007.03.085},
	author = {Pandey, Ganesh and Dumbre, Shrinivas G. and Pal, Sujit and Khan, Mohammad Islam and Shabab, A.}
}
@article { ISI:000315758900005,
	title = {Alpha-trimethylsilylmethylamine radical cation in the synthesis of cyclic amines and beyond},
	journal = {Chimia},
	volume = {67},
	number = {1-2},
	year = {2013},
	month = {FEB},
	pages = {30-38},
	publisher = {SWISS CHEMICAL SOC},
	address = {SCHWARZTORSTRASSE 9, CH-3007 BERN, SWITZERLAND},
	abstract = {<p>The evolution of chemistry associated with the photoinduced electron transfer (PET)-generated alpha-trimethylsilylmethylamine radical cation cyclization to a tethered olefin to synthesize byclic amine structural frame works is presented in chronological order. The importance of this interesting chemistry is demonstrated by the synthesis of several novel glycosidase inhibitors.</p>},
	keywords = {1-N-Iminosugars, alpha-Amine radical, alpha-Trimethylsilyl methylamine radical cation, Glycosidase inhibitors, Photoinduced electron transfer (PET)},
	issn = {0009-4293},
	doi = {10.2533/chimia.2013.30},
	author = {Pandey, Ganesh and Dey, Debasis and Gadre, Smita R.}
}
