@article {49329,
	title = {Rational design of zero-dimensional manganese(II) halide hybrids with suppressed melting temperatures},
	journal = {JOURNAL OF PHYSICAL CHEMISTRY C},
	volume = {128},
	year = {2024},
	month = {AUG },
	pages = {14849-14859},
	type = {Journal Article},
	keywords = {ORGANIC-INORGANIC PEROVSKITES, TRANSITION},
	issn = {1932-7447},
	doi = {10.1021/acs.jpcc.4c04444},
	author = {Singh, Shivangi and Marayathungal, Jumana Hasin and Das, Deep Kumar and Khan, Akram Aadil and Bakthavatsalam, Rangarajan and Hathwar, Venkatesha R. and Kundu, Janardan}
}
@article {49933,
	title = {Supercooled liquid phases of luminescent zero dimensional metal halide hybrids},
	journal = {Journal of Physical Chemistry Letters},
	volume = {16},
	year = {2025},
	month = {SEP},
	pages = {9391-9400},
	type = {Article},
	abstract = {<p>
	Chemical design of metal halide hybrids (MHHs) with suppressed melting point (T-m) allows access to glassy phases from their liquid-melts. Thermal phase change (crystal-melt-glass) properties of glassy MHHs (with glass transition temperature T-g \&gt; room temperature) have been exploited for device applications. However, room temperature stable supercooled liquid (SCL) MHHs (with T-g \&lt; room temperature), originating from glass-SCL phase change, remain inaccessible. Here, a molecular design strategy is reported to access ambient stable, melt-processable, SCL multimetallic bromide hybrids (Mn2+,Cd2+; Mn2+,Zn2+; Benzyltributylammonium) with low T-g (15-16 degrees C), low T-m (90-100 degrees C), green luminescence, and high optical transparency. Structural, optical, thermal, and computational analyses highlight chemical design principles and support dopant (Mn2+) based luminescence. Rheological measurements confirm the SCL phase that shows thermal hysteresis and estimate relaxation time scales. This work provides a new material platform showcasing enhanced melt-processability for fabrication of moldable devices, unravelling chemical makeup-property correlation and expanding the material phase types of MHHs.</p>
},
	issn = {1948-7185},
	doi = {10.1021/acs.jpclett.5c01979},
	author = {Kumar Das, Deep and Marayathungal, Jumana Hasin and Palakkolil, Athira and Sarma, Dhritismita and Khan, Akram Aadil and Kumar, M. Praveen and Kudlu, Ashwath and Choudhary, Mahendra and Hathwar, Venkatesha R. and Pujala, Ravi Kumar and Mahata, Arup and Kundu, Janardan}
}
