@article {49306,
	title = {Organocatalytic route to the enantioselective synthesis of syn/ anti-α-hydrazino-γ-fluoro alcohols},
	journal = {Tetrahedron Letters},
	volume = {145},
	year = {2024},
	month = {JUL},
	pages = {155179},
	type = {Article},
	abstract = {<p>
	A general organocatalytic method has been developed for the asymmetric synthesis of alpha-hydrazino-gamma-fluoro alcohols, a precursor to syn/anti-1,3-fluoro amines. The strategy employs alpha-fluorination catalyzed by prolinederived catalyst, (S)-alpha,alpha-bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemetha nol trimethylsilyl ether followed by Horner-Wadsworth-Emmons (HWE) olefination of aldehydes, and proline-catalyzed alpha-amination as the key steps. The title compounds showed excellent diastereoselectivity (up to 99:1) and enantioselectivity (up to 99 \%).</p>
},
	keywords = {alpha-Amination, alpha-Fluorination, diastereoselectivity, Enantioselectivity, HWE olefination, organocatalyst},
	issn = {0040-4039},
	doi = {10.1016/j.tetlet.2024.155179},
	author = {Khonde, Nilesh S. and Said, Madhukar S. and Danve, Shivam S. and Kumar, Pradeep}
}
@article {49776,
	title = {Tetrahydrofuran ring construction through tandem iodocyclizations: synthesis of hagen{\textquoteright}s gland lactones, a pheromone of idea leuconoe , an oxylipid, and related compounds},
	journal = {Synlett},
	volume = {36},
	year = {2025},
	month = {SEP},
	pages = {2299-2303},
	type = {Article},
	abstract = {<p>
	A simple and efficient common route was developed for the syntheses of tetrahydrofuran-ring-containing natural products such as Hagen{\textquoteright}s gland lactones and their epimers, a pheromone of the butterfly Idea leuconoe, an oxylipid, and some valuable synthons. Brown{\textquoteright}s allylation, cross-metathesis, iodocyclization, and a tandem aminoxylation/allylation were employed as key steps in the syntheses.</p>
},
	keywords = {Cross-metathesis, Hagen{\textquoteright}s gland lactone, Iodocyclization, oxylipids, pheromones, tetrahydrofurans},
	issn = {0936-5214},
	doi = {10.1055/a-2550-1785},
	author = {Nookaraju, U. and Danve, Shivam S. and Kumar, Pradeep}
}
