@article {49082,
	title = {Total synthesis and revision of stereochemistry of a natural benzo[g]isochromene stereodiad isolated from rubia philippinensis},
	journal = {Organic Letters},
	volume = {26},
	year = {2024},
	month = {MAR },
	pages = {2574-2579},
	type = {Article},
	abstract = {<p>
	This study presents a total synthesis and revision of the stereochemical configuration of the conformationally flexible natural product benzo[g]isochromene stereodiad alongside its diastereomeric counterparts. The highlights of the synthesis are the TiCl4-mediated diastereoselective aldol reaction, Pd-catalyzed lactonization, and Schmidt glycosidation. Our efforts using total synthesis disclosed herein proved that a previously assigned structure required revision.</p>
},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.4c00553},
	author = {Choudhury, Rahul and Miriyala, Satya Ravi Teja and Resmi, K. R. and Sridhar, Balasubramanian and Kasa, S. R. Krishna Murthy and Reddy, D. Srinivasa}
}
