@article {47379,
	title = {Diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene},
	journal = {Chemical Communications},
	volume = {57},
	year = {2021},
	month = {MAY},
	pages = {5008-5011},
	type = {Article},
	abstract = {<p>{The reactivity of NOBF4 towards silylene, disilene, germylene, stannylenes has been described. Smooth syntheses of compounds of composition [PhC(NtBu)(2)E(= O -\&gt; BF3)N(SiMe3)(2)</p>},
	issn = {1359-7345},
	doi = {10.1039/d1cc01034d, Early Access Date = APR 2021},
	author = {Parvin, Nasrina and Sen, Nilanjana and Muhasina, Puthan Veetil and Tothadi, Srinu and Parameswaran, Pattiyil and Khan, Shabana}
}
@article {47724,
	title = {Synthesis and application of silylene-stabilized low-coordinate Ag(I)-arene cationic complexes},
	journal = {Organometallics},
	volume = {40},
	year = {2021},
	month = {JUN },
	pages = {1626-1632},
	type = {Article},
	abstract = {We report the first examples of N-heterocyclic silylene-stabilized monocoordinate Ag(I) cationic complexes weakly bound to the free arene rings (C6H6, C6Me6, and C7H8). Further, the application of these electrophilic Ag(I) complexes as catalysts has been investigated toward A(3)-coupling reactions, which afforded a series of propargylamines in good to excellent yields with low catalyst loading under a solvent-free condition (19 examples).},
	issn = {0276-7333},
	doi = {10.1021/acs.organomet.1c00083},
	author = {Parvin, Nasrina and Sen, Nilanjana and Tothadi, Srinu and Muhammed, Shahila and Parameswaran, Pattiyil and Khan, Shabana}
}
@article {48215,
	title = {First-row transition metal complexes of a phosphine-silylene- based hybrid ligand},
	journal = {Inorganic Chemistry},
	volume = {61},
	year = {2022},
	month = {AUG},
	pages = {13330-13341},
	type = {Article},
	abstract = {<p>
	We have prepared two new silylene-phosphine-based hybrid ligands Si{N(R)C6H4(PPh2)}{PhC((NBu)-Bu-t)(2)} [R = TMS {trimethylsilyl} (1) and TBDMS {tert-butyldimethylsilyl} (2)], which possess two donor sites. Furthermore, the treatment of the bidentate ligand 1 with base metal halides {FeBr2, CoBr2, NiCl(2)middotdme [nickel chloride(II) ethylene glycol dimethyl ether]} and 2 with NiBr(2)middotdme [nickel bromide(II) ethylene glycol dimethyl ether] afforded four-coordinate six-membered metal complexes 3-6, respectively, which feature coordination from both Si(II) and P(III) sites. Subsequently, complexes 3 [(FeBr2)Si{N(SiMe3)C6H4(PPh2)}{PhC((NBu)-Bu-t)(2)}], 4 [(CoBr2)Si{N(SiMe3)C6H4(PPh2)}{PhC((NBu)-Bu-t)(2)}], 5 [(NiCl2)Si{N(SiMe3)C6H4(PPh2)}{PhC((NBu)-Bu-t)(2)}], and 6 [(NiBr2)Si{N((SiBuMe2)-Bu-t)C6H4(PPh2)}{PhC((NBu)-Bu-t)(2)}] are studied for their redox and magnetic properties with the help of UV-vis spectroscopy, cyclic voltammetry, SQUID magnetometry, and theoretical calculations. Complexes 3-6 were found to display a paramagnetic behavior. All the compounds are well established by single-crystal X-ray diffraction studies.</p>
},
	issn = {0020-1669},
	doi = {10.1021/acs.inorgchem.2c01233},
	author = {Akhtar, Ruksana and Kaulage, Sandeep H. and Sangole, Mayur P. and Tothadi, Srinu and Parvathy, Parameswaran and Parameswaran, Pattiyil and Singh, Kirandeep and Khan, Shabana}
}
