@article {46934,
	title = {Gold and hypervalent iodine(iii): liaisons over a decade for electrophilic functional group transfer reactions},
	journal = {Chemical Communications},
	volume = {56},
	year = {2020},
	month = {MAR },
	pages = {2677-2690},
	type = {Article},
	abstract = {<p>Over the last two decades, hypervalent iodine(iii) reagents have evolved from being {\textquoteleft}bonding curiosities{\textquoteright} to mainstream reagents in organic synthesis, in particular, electrophilic functional group transfer reactions. In this context, gold catalysts have not only emerged as a unique toolbox to facilitate such reactions (especially alkynylations) but also opened new possibilities with their different modes of reactivities for other functional group transfer reactions (acetoxylations and arylations). This feature article critically summarizes hitherto all such Au-catalyzed electrophilic functional group transfer reactions with hypervalent iodine(iii) reagents, emphasizing their mechanistic aspects.</p>
},
	issn = {1359-7345},
	doi = {10.1039/d0cc00106f},
	author = {Banerjee, Somsuvra and Bhoyare, Vivek W. and Patil, Nitin T.}
}
@article {48191,
	title = {Enantioselective Au(I)/Au(III) redox catalysis enabled by chiral (P,N)-ligands},
	journal = {Journal of the American Chemical Society},
	volume = {144},
	year = {2022},
	month = {APR},
	pages = {7089-7095},
	type = {Article},
	abstract = {<p>
	Presented herein is the first report of enantioselective Au(I)/Au(III) redox catalysis, enabled by a newly designed hemilabile chiral (P,N)-ligand (ChetPhos). The potential of this concept has been demonstrated by the development of enantioselective 1,2-oxyarylation and 1,2-aminoarylation of alkenes which provided direct access to the medicinally relevant 3-oxy- and 3-aminochromans (up to 88\% yield and 99\% ee). DFT studies were carried out to unravel the enantiodetermining step, which revealed that the stronger trans influence of phosphorus allows selective positioning of the substrate in the C-2-symmetric chiral environment present around nitrogen, imparting a high level of enantioselectivity.</p>
},
	issn = {0002-7863},
	doi = {10.1021/jacs.2c02799},
	author = {Chintawar, Chetan C. and Bhoyare, Vivek W. and Mane, Manoj V. and Patil, Nitin T.}
}
