@article {46921,
	title = {Construction of unique SCF3-containing building blocks via allylic alkylation of Morita-Baylis-Hillman adducts},
	journal = {Organic \& Biomolecular Chemistry},
	volume = {18},
	year = {2020},
	month = {MAR },
	pages = {2085-2093},
	type = {Article},
	abstract = {<p>Lewis base-catalyzed allylic alkylation of Morita-Baylis-Hillman adducts with alpha-SCF3 ketones has been demonstrated. The developed strategy provides efficient access to a series of highly functionalized scaffolds featuring trifluoromethanesufinyl motif on a stereogenic carbon.</p>
},
	issn = {1477-0520},
	doi = {10.1039/d0ob00104j},
	author = {Halder, Priyanka and Pol, Mahesh D. and Ahire, Milind M. and Mhaske, Santosh B.}
}
@article {47651,
	title = {Annulation of enals with carbamoylpropiolates via NHC-catalyzed enolate pathway: access to functionalized maleimides/iso-maleimides and synthesis of aspergillus FH-X-213},
	journal = {Journal of Organic Chemistry},
	volume = {86},
	year = {2021},
	month = {JUL },
	pages = {9466-9477},
	type = {Article},
	abstract = {Herein we report the N-heterocyclic carbene (NHC)-catalyzed [3 + 2] annulation of alpha,beta-unsaturated aldehydes with carbamoylpropiolates via an unusual enolate pathway leading to the construction of highly functionalized maleimides or isomaleimides. The electronic effect imposed by the alkyl/aryl group present on the amide nitrogen of carbamoylpropiolates plays a crucial role in the selective formation of these important five-membered heterocyclic building blocks. The developed protocol is mild and tolerates a wide range of substituents on both substrates. The application of this protocol in the synthesis of the antibacterial natural product Aspergillus FH-X-213 has also been demonstrated.},
	issn = {0022-3263},
	doi = {10.1021/acs.joc.1c00782},
	author = {Viveki, Amol B. and Pol, Mahesh D. and Halder, Priyanka and Sonavane, Sameer R. and Mhaske, Santosh B.}
}
@article {48700,
	title = {PIDA-mediated N-N bond formation to access pyrazolidine-3,5-diones: a novel process for uricosuric agents G-25671 and sulfinpyrazone},
	journal = {Chemical Communications},
	volume = {59},
	year = {2023},
	month = {JUN },
	pages = {8242-8245},
	type = {Article},
	abstract = {<p>
	Traditionally, toxic and expensive hydrazine building blocks are required to construct pharmaceutically important pyrazolidine-3,5-diones. Herein, we have described a novel method for their synthesis based on metal-free oxidative dehydrogenative N-N bond formation by PIDA-mediated reaction of easily accessible dianilide precursors. The developed mild reaction protocol features a good functional group tolerance and scalability. The application of this method is demonstrated by offering a unique route for the synthesis of uricosuric agents G-25671 and sulfinpyrazone from inexpensive starting material aniline via smooth functionalization of the well-designed diversity-oriented cyclopropyl key intermediate.</p>
},
	issn = {1359-7345},
	doi = {10.1039/d3cc02078a},
	author = {Halder, Priyanka and Mhaske, Santosh B.}
}
