@article {47397,
	title = {Hypervalent iodine(iii) induced oxidative olefination of benzylamines using Wittig reagents},
	journal = {New Journal of Chemistry},
	volume = {45},
	year = {2021},
	month = {MAY},
	pages = {8806-8813},
	type = {Article},
	abstract = {<p>We have developed hypervalent iodine(iii) induced oxidative olefination of primary and secondary benzylamines using 2C-Wittig reagents, which provides easy access to alpha,beta-unsaturated esters. Mild reaction conditions, good to excellent yields with high (E) selectivity, and a broad substrate scope are the key features of this reaction. We have successfully carried out the gram-scale synthesis of alpha,beta-unsaturated esters.</p>},
	issn = {1144-0546},
	doi = {10.1039/d1nj01170g, Early Access Date = APR 2021},
	author = {Ramavath, Vijayalakshmi and Rupanawar, Bapurao D. and More, Satish G. and Bansode, Ajay H. and Suryavanshi, Gurunath}
}
@article {49412,
	title = {Hypervalent-iodine-mediated base-free oxidative olefination of benzylic amines to access α,β-unsaturated ketones},
	journal = {Synlett},
	volume = {36},
	year = {2025},
	month = {AUG},
	pages = {556-560},
	type = {Article},
	abstract = {<p>
	We report a one-pot base-free protocol for the oxidative olefination of benzylic amines promoted by a hypervalent iodine reagent for the synthesis of alpha,beta-unsaturated ketones. Mechanistically, (diacetoxyiodo)benzene oxidizes the benzylic amine to the corresponding imine, which, on reaction with a phenacyl(triphenyl)phosphonium bromide salt and an in situ generated acetoxy anion leads to an alpha,beta-unsaturated ketone. A wide range of alpha,beta-unsaturated ketones were easily accessed through direct oxidative olefination of substituted benzylic amines in good to excellent yields and with high E -selectivity.</p>
},
	keywords = {benzylic amines, enones, hypervalent iodine, olefination, Oxidation},
	issn = {0936-5214},
	doi = {10.1055/s-0043-1775392},
	author = {Rupanawar, Bapurao D. and Bansode, Ajay H. and Suryavanshi, Gurunath}
}
