@article { ISI:000338980500002,
	title = {Formation of a room temperature stable Fe-V(O) complex: reactivity toward unactivated C-H bonds},
	journal = {Journal of American Chemical Society},
	volume = {136},
	number = {27},
	year = {2014},
	month = {JUL},
	pages = {9524-9527},
	publisher = {AMER CHEMICAL SOC},
	type = {Article},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>An Fe-V(O) complex has been synthesized from equimolar solutions of (Et4N)(2)[Fe-III(Cl)(biuretamide)] and mCPBA in CH3CN at room temperature. The Fe-V(O) complex has been characterized by UV-vis, EPR, Mossbauer, and HRMS and shown to be capable of oxidizing a series of alkanes having C-H bond dissociation energies ranging from 99.3 kcal mol(-1) (cyclohexane) to 84.5 kcal mori (cumene). Linearity in the Bell-Evans-Polayni graph and the finding of a large kinetic isotope effect suggest that hydrogen abstraction is engaged the rate-determining step.</p>},
	issn = {0002-7863},
	doi = {10.1021/ja412537m},
	author = {Ghosh, Munmun and Singh, Kundan K. and Panda, Chakadola and Weitz, Andrew and Hendrich, Michael P. and Collins, Terrence J. and Dhar, Basab B. and Sen Gupta, Sayam}
}
@article { ISI:000352508300032,
	title = {Reactivity and operational stability of N-Tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2O2: synthesis and x-ray structure of an N-Phenyl TAML},
	journal = {Chemistry A-European Journal},
	volume = {21},
	number = {16},
	year = {2015},
	month = {APR},
	pages = {6226-6233},
	publisher = {WILEY-V C H VERLAG GMBH},
	type = {Article},
	address = {BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY},
	abstract = {<p>{The catalytic activity of the N-tailed (biuret) TAML (tetraamido macrocyclic ligand) activators [Fe{4-XC6H3-1,2-(NCOCMe2NCO)(2)NR}Cl](2-) (3; N atoms in boldface are coordinated to the central iron atom; the same nomenclature is used in for compounds 1 and 2 below), [X</p>},
	keywords = {Hydrogen peroxide, iron, kinetics, Oxidation, reaction mechanisms},
	issn = {0947-6539},
	doi = {10.1002/chem.201406061},
	author = {Warner, Genoa R. and Mills, Matthew R. and Enslin, Clarissa and Pattanayak, Shantanu and Panda, Chakadola and Panda, Tamas Kumar and Sen Gupta, Sayam and Ryabov, Alexander D. and Collins, Terrence J.}
}
