@article {45518,
	title = {Gold-catalyzed 1,2-oxyalkynylation of N-Allenamides with ethylnylbenziodoxolones},
	journal = {Organic Letters},
	volume = {21},
	year = {2019},
	month = {JAN},
	pages = {180-184},
	type = {Article},
	abstract = {<p>A gold-catalyzed 1,2-oxyalkynylation of N-allenamides with ethylnylbenziodoxolones (EBXs) has been achieved for the first time. The reaction, which follows a redox-neutral Au(I)/Au(III) catalytic pathway, was enabled in an attempt to exhaust the EBX reagents atom-economically by putting the nucleophilic carboxylate part of EBXs to appropriate use. This constitutes the first example for gold-catalyzed beta-alkynylation of N-allenamides to construct highly valuable 1,3-enynes. The potential of the sequence is further documented by some follow-up transformations.</p>},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.8b03651},
	author = {Banerjee, Somsuvra and Senthilkumar, Beeran and Patil, Nitin T.}
}
@article {46819,
	title = {Gold-catalyzed alkynylative meyer-schuster rearrangement},
	journal = {Organic Letters},
	volume = {22},
	year = {2020},
	month = {JUN},
	pages = {4792-4796},
	type = {Article},
	abstract = {<p>By applying the {\textquoteleft}{\textquoteleft}interplay{\textquoteright}{\textquoteright} mode, which consolidates two key reactivity modes of gold catalysis, namely pi-activation mode and cross-coupling mode, the first alkynylative Meyer-Schuster rearrangement is designed and successfully implemented. The current protocol gives straightforward access to enynones, a highly valuable building block, from easily available propargyl alcohol feedstocks. Control experiments suggest an Au(III) catalyst triggers the Meyer-Schuster rearrangement, whereas monitoring the reaction with ESI-HRMS provided strong evidence in favor of a key alkynylgold(III) intermediate which supports the proposed {\textquoteleft}{\textquoteleft}interplay{\textquoteright}{\textquoteright} scenario.</p>
},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.0c01596},
	author = {Banerjee, Somsuvra and Ambegave, Shivhar B. and Mule, Ravindra D. and Senthilkumar, Beeran and Patil, Nitin T.}
}
