@article { ISI:000356324000001,
	title = {Radical-mediated dehydrative preparation of cyclic imides using (NH4)(2)S2O8-DMSO: application to the synthesis of vernakalant},
	journal = {Beilstein Journal of Organic Chemistry},
	volume = {11},
	year = {2015},
	month = {JUN},
	pages = {1008-1016},
	publisher = {BEILSTEIN-INSTITUT},
	address = {TRAKEHNER STRASSE 7-9, FRANKFURT AM MAIN, 60487, GERMANY},
	abstract = {<p>Ammonium persulfate-dimethyl sulfoxide (APS-DMSO) has been developed as an efficient and new dehydrating reagent for a convenient one-pot process for the synthesis of miscellaneous cyclic imides in high yields starting from readily available primary amines and cyclic anhydrides. A plausible radical mechanism involving DMSO has been proposed. The application of this facile one-pot imide forming process has been demonstrated for a practical synthesis of vernakalant.</p>},
	keywords = {APS-DMSO, imides, practical synthesis, radical-mediated, vernakalant},
	issn = {1860-5397},
	doi = {10.3762/bjoc.11.113},
	author = {Garad, Dnyaneshwar N. and Tanpure, Subhash D. and Mhaske, Santosh B.}
}
@article { ISI:000380182400037,
	title = {Radical beckmann rearrangement and its application in the formal total synthesis of antimalarial natural product isocryptolepine via C-H activation},
	journal = {Organic Letters},
	volume = {18},
	number = {14},
	year = {2016},
	month = {JUL},
	pages = {3450-3453},
	publisher = {AMER CHEMICAL SOC},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>The Beckmann rearrangement of ketoximes, mediated by ammonium persulfate-dimethyl sulfoxide as a reagent, has been achieved under neutral conditions. Based on the radical trapping and O-18-labeling experiments, the transformation follows a mechanism involving a radical pathway. The scope and generality of the developed protocol has been demonstrated by 19 examples. The developed protocol and Pd-catalyzed intramolecular double C-H activation were used as key steps in the formal total synthesis of antimalarial natural product isocryptolepine.</p>},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.6b01634},
	author = {Mahajan, Pankaj S. and Humne, Vivek T. and Tanpure, Subhash D. and Mhaske, Santosh B.}
}
