@article {46700,
	title = {Oxime ligands for Pd catalysis of the mizoroki-heck reaction, suzuki-miyaura coupling \& annulation reactions},
	journal = {Synthetic Communications},
	volume = {51},
	year = {2021},
	month = {JAN },
	pages = {308-316},
	type = {Article},
	abstract = {<p>Monodentate and bidentate chelating oximes are readily available ligands for the Pd catalysis of the Mizoroki-Heck reaction and the Suzuki coupling. High yields were obtained in the Suzuki coupling in aqueous dioxane with TBABr as additive. The oximes can be easily synthesized from the corresponding ketones or aldehydes and thus provide a very large number of nitrogen-based ligands. They have the advantage of not undergoing oxidative degradation, common for phosphine ligands. Chelating oximes with Pd(OAc)(2), activate aryl iodides to give high yields of the substitution products in the Mizoroki-Heck reactions as well as the Suzuki coupling. Acetophenone oxime ligand with Pd(OAc)(2), catalyzed the reaction of aryl iodides with 1,2-disubstituted alkenes in moderate to high yields. As a test example, the LaRock indole annulation and synthesis of isocoumarin were achieved with acetophenone oxime ligand and Pd(OAc)(2)in high yields.</p>
},
	keywords = {Isocoumarin, LaRock annulation, Mizoroki-Heck reaction, oximes, Suzuki coupling},
	issn = {0039-7911},
	doi = {10.1080/00397911.2020.1826969, Early Access Date = SEP 2020},
	author = {Bangar, Pronnoy G. and Nahide, Pradip D. and Meroliya, Heena K. and Waghmode, Shobha A. and Iyer, Suresh}
}
@article {47816,
	title = {Oxime ligands for Pd catalysis of the mizoroki{\textendash}heck reaction, Suzuki{\textendash}Miyaura coupling \& annulation reactions},
	journal = {Synthetic Communications},
	volume = {51},
	year = {2021},
	month = {JAN},
	pages = {308-316},
	type = {Article},
	abstract = {AbstractMonodentate and bidentate chelating oximes are readily available ligands for the Pd catalysis of the Mizoroki{\textendash}Heck reaction and the Suzuki coupling. High yields were obtained in the Suzuki coupling in aqueous dioxane with TBABr as additive. The oximes can be easily synthesized from the corresponding ketones or aldehydes and thus provide a very large number of nitrogen-based ligands. They have the advantage of not undergoing oxidative degradation, common for phosphine ligands. Chelating oximes with Pd(OAc)2, activate aryl iodides to give high yields of the substitution products in the Mizoroki{\textendash}Heck reactions as well as the Suzuki coupling. Acetophenone oxime ligand with Pd(OAc)2, catalyzed the reaction of aryl iodides with 1,2-disubstituted alkenes in moderate to high yields. As a test example, the LaRock indole annulation and synthesis of isocoumarin were achieved with acetophenone oxime ligand and Pd(OAc)2 in high yields.},
	doi = {10.1080/00397911.2020.1826969},
	author = {Bangar, Pronnoy G. and Nahide, Pradip D. and Meroliya, Heena K. and Waghmode, Shobha A. and Iyer, Suresh}
}
@article {49644,
	title = {Oxime ligands: organometallic synthesis and catalysis},
	journal = {SYNTHETIC COMMUNICATIONS},
	volume = {54},
	year = {2024},
	month = {MAR},
	pages = {417-459},
	type = {Review},
	abstract = {<p>
	Ligands are at the heart of coordination chemistry. They conjure the magic of transition metals expressed in organometallic catalysis. Phosphine or P-ligands have found vast utility in transition metal chemistry, though demanding tedious synthesis. Several N, S-based ligands also find application in organometallic chemistry. Oximes are easily derived from aldehydes and ketones by simple reactions with hydroxylamine. Thus, an extensive library of oximes is available with different structural and electronic variations essential for coordination chemistry and catalysis. Several compounds with complex structural features, unavailable for phosphorous ligands, can be readily converted into active oxime ligands in a single derivatization step. Oxime ligands and metal complexes are applied in synthesizing diverse organic molecules and thus versatile ligands in organotransition metal chemistry.</p>
},
	keywords = {cobaloxime, Cross-coupling, oxime palladacycles, oximes, radical cyclization},
	issn = {0039-7911},
	doi = {10.1080/00397911.2023.2297038},
	author = {Iyer, Suresh}
}
