@article {48042,
	title = {Metal- and light-free direct C-3 ketoalkylation of quinoxalin-2(1H)-ones with cyclopropanols in aqueous medium},
	journal = {ChemistrySelect},
	volume = {7},
	year = {2022},
	month = {OCT},
	pages = {e202203597},
	type = {Article},
	abstract = {<p>
	Direct oxidative C-3 ketoalkylation of quinoxalin-2(1H)-ones with cyclopropanols using ammonium persulfate in an aqueous medium has been achieved in a moderate to good yield. The reaction does not require metals, light-source, or catalysts to facilitate the reaction and could be efficiently utilized to construct a wide range of biologically relevant 3-ketoalkylated quinoxalin-2(1H)-ones.</p>
},
	keywords = {aqueous medium, cyclopropanols, ketoalkylation, metal-free, quinoxalin-2(1H)-ones},
	issn = {2365-6549},
	doi = {10.1002/slct.202203597},
	author = {More, Devidas A. and Mujahid, M. and Muthukrishnan, M.}
}
@article {49562,
	title = {Iron mediated oxidative ring opening-homocoupling of cyclopropanols: facile access to 1,6-diketones},
	journal = {ChemistrySelect},
	volume = {10},
	year = {2025},
	month = {MAY},
	pages = {e202501745},
	type = {Article},
	abstract = {<p>
	We have developed a new approach for the synthesis of 1,6-diketones via iron-catalyzed ring opening of cyclopropanol with a nontoxic, inexpensive iron catalyst under open-air conditions. This method eliminates the need for additives and employs tert-butanol as an eco-friendly solvent. This methodology allows rapid access to a variety of symmetrical 1,6-diketones under mild conditions. Preliminary mechanistic studies revealed the involvement of radical pathways.</p>
},
	keywords = {1, 6-Diketone synthesis, C \& horbar, C bond cleavage, cyclopropanols, Homocoupling, Iron mediated},
	issn = {2365-6549},
	doi = {10.1002/slct.202501745},
	author = {Shinde, Ravi A. and Shirsath, Sachin and Muthukrishnan, M.}
}
