@article {43998,
	title = {Removal of endrin and dieldrin isomeric pesticides through stereoselective adsorption behavior on the graphene oxide-magnetic nanoparticles},
	journal = {Environmental Science and Pollution Research},
	year = {2017},
	month = {SEP},
	pages = {1-9},
	type = {Article in Press},
	abstract = {<p>A novel stereoselective removal behavior of isomeric endrin and dieldrin pesticides from sample solution is demonstrated using nanocomposite of graphene oxide (GO) and iron oxide (Fe3O4) magnetic nanoparticles (MNPs). The removal efficiency of endrin and dieldrin was found higher when GO-MNPs was used as a separating probe than the individual use of GO and MNPs. The removal efficiency of both the pesticides was found to be more favorable when the dosage amount of GO-MNPs was 30 mg for 30-min contact time with pH 4.0 at room temperature. The good correlation of determination (R2) with 0.975 and 0.973 values obtained for endrin and dieldrin, respectively demonstrated a well fitting of Langmuir adsorption isotherm model. The higher removal percentage (86.0\%) and higher slope value of Langmuir adsorption isotherm were estimated for endrin compared to dieldrin (74.0\%). The reason for higher adsorption percentage of endrin is due to the endo-position of oxygen atom in molecule favors more interaction of molecules with GO-MNPs compared to the exo-position of oxygen present in dieldrin. In addition, the higher value of R2 for endrin and dieldrin demonstrated better suitability of pseudo-first-order and pseudo-second-order kinetic models, respectively. The advantages of the present method are use of simple UV-vis spectrophotometry for monitoring and low-cost use of GO-MNPs nanomaterial for the removal of pesticides from sample solution. {\textcopyright} 2017 Springer-Verlag GmbH Germany</p>},
	keywords = {Dieldrin, Endrin, Isomeric Pesticides, Removal},
	doi = { 10.1007/s11356-017-0159-z},
	author = {Shrivas, K. and Ghosale, A. and Nirmalkar, N. and Srivastava, A and Singh, S. K. and Shinde, S. S.}
}
@inbook {45775,
	title = {Synthesis of fluorinated heterocycles via multicomponent reactions},
	booktitle = {Multicomponent reactions: synthesis of bioactive heterocycles},
	year = {2017},
	pages = {183-199},
	publisher = {CRC Press},
	organization = {CRC Press},
	chapter = {Synthesis of fluorinated heterocycles via multicomponent reactions},
	abstract = {Fluorine is one of the most important elements in the periodic table because it is the most electronegative element, makes the strongest C-F bond, and is more polarized in organic synthesis. These unique and distinctive properties of fluorine make it very useful and widely applicable in the pharmaceutical and agrochemical industries. Hydrogen replaced with the fluorine of an organic compound can tune the pharmacokinetic and pharmacological properties of the molecule, which improve solubility, membrane permeability, 184metabolic stability, and receptor-binding properties compared with nonfluorinated analogs.1 Due to these unique properties of fluorine, organofluorine compounds are very applicative in medicinal, pharmaceutical, agrochemical, and material chemistry. This wide applicability of fluorine and organofluorine compounds attracts the attention of researchers and chemists. Labeled fluorine-18 is one of the most commonly used positron emitting radioisotopes in positron emission tomography (PET) imaging technology, which can detect presymptomatic biochemical changes in body tissues. In addition to its use in PET-CT, fluorine is used in preparation of chemically resistant polymer materials such as polytetrafluoroethylene (Teflon) or polarity to piezoelectric material such as polyvinylidene fluoride and organic liquid crystals for displays. Because of these many advantages of fluorine, organic chemists have developed various methods to introduce fluorine in organic molecules. During the last two decades, numerous organofluorine heterocyclics have been developed; in this chapter, we have summarized synthesis of multicomponent reactions (MCRs) in application of fluorine compound synthesis.},
	issn = { 978-149873419-6},
	doi = {10.1201/9781315369754},
	author = {Shinde, S. S. and Thore, S. N. and Pawar, R. P. and Ameta, K. L. and Patil, S. N.}
}
@article {45603,
	title = {Catalytic and efficient synthesis of optically active terminal epoxides and 1,2-diols using a new lanthanum triflate assisted C1-symmetric bimetallic chiral salen cobalt complex},
	journal = {Letters in Organic Chemistry},
	volume = {15 },
	year = {2018},
	pages = {960 - 966},
	type = {Article},
	abstract = {The catalytic asymmetric synthesis of terminal epoxides and 1,2-diols via a hydrolytic kinetic resolution of racemic terminal epoxides using a new bimetallic chiral salen CoIII complex incorporated with La(OTf)3 as a catalyst is reported. The new bimetallic chiral salen CoIII complex bearing La(OTf)3 was prepared in a one-pot procedure by activation and bimetallic complex formation from the inactive Jacobsen chiral salen CoII complex (salen = N, N'-bis(3,5-di-tert-butylsalicylidene)-1,2- cyclohexane-diamine). We observed that C1-symmetric chiral bimetallic Co-complex coordinated with La(OTf)3 works as a chiral catalyst and remarkably increased the reactivity and enantioselectivity in the hydrolytic kinetic resolution of terminal epoxides compared to its monometallic analogues. La(OTf)3 plays a crucial role as an achiral Lewis acid in this process, which is supported by the experimental observation presented. To explore the absolute configuration of glycidyl butyrate a vibrational circular dichroism (VCD) spectra was calculated using density functional theory.},
	doi = {10.2174/1570178615666171212144938},
	author = {Patel, D. and Thakur, S. S. and Shinde, S. S. and Kumar, P.}
}
@article {45531,
	title = {One-pot sequential bromination and fluorination to access 3-fluoroimidazo[1,2-a]pyridines from arylketones},
	journal = {European Journal Of Organic Chemistry},
	volume = {2018},
	year = {2018},
	month = {JUL},
	pages = {3432-3436},
	type = {Article},
	abstract = {3-Fluoro-2-arylimidazo[1,2-a]pyridines were selectively synthesised in one-pot from acetophenones and 2-aminopyridines under mild conditions. The sequence of reactions involved bromination, condensation, and late-stage fluorination. Two halogenating reagents play key roles in the process. We found that tetrabutylammonium tribromide and SelectfluorTM gave excellent yields of the desired products in the one-pot sequential reaction. {\textcopyright} 2018 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim},
	isbn = {1434193X},
	doi = {10.1002/ejoc.201800578},
	author = {Udavant, R. N. and Yadav, A. R. and Shinde, S. S.}
}
