@article {44612,
	title = {Organocatalyst bound -aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions},
	journal = {Organic \& Biomolecular Chemistry},
	volume = {16},
	year = {2018},
	month = {JUL},
	pages = {5081-5085},
	abstract = {<p>A catalyst bound -aminoalkyl radical intermediate from iminium is developed to control its formation and reactivity with aerobic oxygen. The influence of the catalyst was demonstrated via the ease of radical intermediate formation and its subsequent reactivity, including the first catalyst-controlled enantioselective aerobic oxidation with a chiral phosphite catalyst.</p>},
	issn = {1477-0520},
	doi = {10.1039/c8ob01032c},
	author = {Motaleb, Abdul and Bera, Asish and Maity, Pradip}
}
@article {48260,
	title = {Organophosphites: an addition to the arsenal of organocatalysts},
	journal = {European Journal of Organic Chemistry},
	volume = {26},
	year = {2023},
	month = {JAN},
	type = {Review},
	abstract = {<p>
	Organophosphites are nucleophilic in nature and can act as a good leaving group owing to the stability of the phosphite anion. This dual reactivity makes them good candidates for nucleophilic organocatalysis. However, phosphites were introduced only in 2004 as the umpolung catalyst for acylsilane substrates utilizing sequential Brook rearrangements. Very recently, phosphites have been reported to catalyze aza-rearrangements and radical reactions. In this review, we discuss the reactivity parameters to understand its lack of use, as well as the potential for catalysis.</p>
},
	keywords = {acylradical, azaacyl equivalent, cylanion, organocatalysis, phosphite},
	issn = {1434-193X},
	doi = {10.1002/ejoc.202201238},
	author = {Baral, Nilofar and Rani, Soniya and Saikia, Pinku and Maity, Pradip}
}
