@article {43461,
	title = {Iron complex catalyzed selective C-H bond oxidation with broad substrate scope},
	journal = {Organic Letters},
	volume = {19},
	year = {2017},
	month = {FEB},
	pages = {746-749},
	abstract = {<p>The use of a peroxidase-mimicking Fe complex has been reported on the basis of the biuret-modified TAML macrocyclic ligand {\textquoteright}framework (Fe-bTAML) as a catalyst to perform selective oxidation of unactivated 3 degrees C-H bonds and activated 2 degrees C-H bonds with low catalyst loading (1 mol \%) and high product yield (excellent mass balance) under near neutral conditions and broad substrate scope (18 substrates which includes arenes, heteroaromatics, and polar functional groups). Aliphatic C-H oxidation of 3 and 2 sites of complex substrates was achieved with predictable selectivity using steric, electronic, and stereoelectronic rules that govern site selectivity, which included oxidation of (+)-artemisinin to (+)-10 beta-hydroxyartemisinin. Mechanistic studies indicate Fe-V(O) to be the active oxidant during these reactions.</p>},
	doi = {10.1021/acs.orglett.6b03359},
	author = {Jana, Sandipan and Ghosh, Munmun and Ambule, Mayur and Sen Gupta, Sayam}
}
@article {49269,
	title = {Solvent-free hydroxylation of unactivated C-H bonds in small molecules and macromolecules by a Fe complex},
	journal = {ACS CATALYSIS},
	volume = {14},
	year = {2024},
	month = {APR },
	pages = {7173-7181},
	keywords = {Ball milling, solid-state C-H hydroxylation},
	issn = {2155-5435},
	doi = {10.1021/acscatal.4c00775},
	author = {Chatterjee, Debasmita and Sajeevan, Amritha and Jana, Sandipan and Birajdar, Rajkumar S. and Chikkali, Samir H. and Sivaram, Swaminathan and Sen Gupta, Sayam}
}
