@article {50182,
	title = {Base mediated sequentialnitrogen insertion and benzotriazolationof p-quinone methides},
	journal = {Journal of Organic Chemistry},
	volume = {91},
	year = {2026},
	month = {JUL},
	pages = {10414-10424},
	type = {Article},
	abstract = {<p>
	Herein, we report a base-mediated, one-pot protocol for the synthesis of functionalized benzotriazole derivatives via in situ generation of benzotriazoles from benzene-1,2-diamines and tert-butyl nitrite. The transformation proceeds through nitrogen insertion, followed by a subsequent 1,6-aza-Michael addition with p-quinone methides, enabling efficient C-N bond formation. Notably, the developed method operates under mild, transition-metal-free conditions and is performed under an open-air atmosphere, offering a practical and environmentally benign approach to structurally diverse benzotriazoles and demonstrated 34 examples of \&lt;= 87\% yield with wide functional group tolerance.</p>
},
	issn = {0022-3263},
	doi = {10.1021/acs.joc.6c00862},
	author = {Mamale, Ajay G. and Ghodake, Balaji M. and Bhattacharya, Asish K.}
}
