@article {49793,
	title = {Tunable, amine-functionalized porous silica catalyst for CO2 transformation into cyclic organic carbonates at atmospheric pressure},
	journal = {Chemistry-A European Journal},
	volume = {31},
	year = {2025},
	month = {AUG },
	type = {Article},
	abstract = {<p>
	A silica catalyst with characteristic features of broad pore size distribution, large pore width and tunable basic sites was synthesized by a one-step green co-condensation synthesis method analogous to SBA-15 synthesis. The surface chemical features of the above catalyst were explored by XPS, N-2 and CO2 adsorption and desorption experiments. The catalyst showed 90\% conversion of styrene oxide (SO) with nearly complete selectivity toward styrene carbonate (SC) in 7 hours under a solvent-free condition at a temperature of 120 degrees C with the aid of co-catalyst tetrabutylammonium bromide (TBAB). Moreover, the catalyst demonstrates versatility with various epoxide substrates, providing valuable insights into the cycloaddition reaction under ambient pressure conditions involving carbon dioxide. The mechanistic details of the catalytic conversion were investigated by the in-situ DRIFT studies and reported here.</p>
},
	keywords = {CO2 fixation, cyclic organic carbonates, heterogeneous catalysis, in-situ FTIR},
	issn = {0947-6539},
	doi = {10.1002/chem.202500873},
	author = {Gorai, Twinkle and Thanasekar, Chandragopal and Kumar, Pawan and Babu, Athira and Kurungot, Sreekumar and Vinod, C. P.}
}
