@article {49775,
	title = {Unified photoredox-catalyzed aerobic oxidative dynamic kinetic asymmetric transformation for C-N atropoisomers mediated by chiral organophosphites},
	journal = {Organic Letters},
	volume = {27},
	year = {2025},
	month = {AUG },
	pages = {8171-8177},
	type = {Article},
	abstract = {<p>
	The synthesis of anilides with a chiral C(=O)-N axis has relied on direct installation of the chiral C(sp2)-N(sp2) bond or enantioselective modification of the peripheral groups. However, these methods are constrained by the size and type of functional groups compatible with each strategy. Herein, we report a dynamic kinetic asymmetric transformation (DYKAT) for the aerobic oxidation of iminium ions to access C(=O)-N axial chirality that addresses those limitations. Furthermore, it eliminates the need for any auxiliary functional groups, which enables us to develop a unified method for the synthesis of atroposelective isoquinolone, lactam, and amide.</p>
},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.5c02273},
	author = {Saikia, Pinku and Aarthika, M. and Bhattacharjya, Ayantika and Maity, Susmita and Bajpai, Priyam and Bera, Asish and Saha, Arindam and Gonnade, Rajesh G. and Vanka, Kumar and Maity, Pradip}
}
