@article {49683,
	title = {Synthesis of diamido N-heterocyclic imines (DAC = NH) via staudinger or reductive N-N bond cleavage approach},
	journal = {Organometallics},
	volume = {44},
	year = {2025},
	month = {MAY},
	pages = {1129-1133},
	type = {Article},
	abstract = {<p>
	This report communicates the first examples of N-heterocyclic imines based on electrophilic diamido carbenes (DACs). While 2 is prepared by classical Staudinger synthesis, 4 is obtained via an unusual reductive N-N bond cleavage of an azine by HCl. The exocyclic C=N bond lengths in 2 and 4 are substantially shorter than those based on N-heterocyclic carbenes and cyclic (alkyl)(amino)carbene reflecting the electrophilic character of DACs.</p>
},
	issn = {0276-7333},
	doi = {10.1021/acs.organomet.5c00120},
	author = {Balayan, Kajal and Sharma, Himanshu and Vanka, Kumar and Gonnade, Rajesh G. and Sen, Sakya S.}
}
