@article {49533,
	title = {Organophotoredox-catalyzed decarboxylative C-O/N/S bond formation: access to ampakine APIs and quinazolinone alkaloids},
	journal = {Organic Letters},
	volume = {27},
	year = {2025},
	month = {APR},
	pages = {3871-3876},
	type = {Article},
	abstract = {<p>
	This study describes a novel and general protocol featuring organophotoredox-catalyzed intramolecular decarboxylative construction of carbon-heteroatom (oxygen, nitrogen, and sulfur) bonds, enabling direct access to ampakine APIs (CX-614 and CX-554), quinazolinone alkaloids (deoxyvasicinone and mackinazolinone), and thiazinone scaffolds as well as their congeners with broad functional group tolerance and scalability. Mechanistic studies suggest a radical-polar crossover pathway via single-electron oxidation.</p>
},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.5c00565},
	author = {Sonavane, Sameer R. and Kale, Tushar B. and Bhatt, Gaurang J. and Mhaske, Santosh B.}
}
