@article {49427,
	title = {Hybrid silylene-Pd catalyst: efficient C-N cross-coupling of sterically bulky amines and chiral amines},
	journal = {Chemical Communications},
	volume = {60},
	year = {2024},
	month = {SEP },
	pages = {9958-9961},
	type = {Article},
	abstract = {<p>
	Herein, we report a catalytic system with N-heterocyclic silylene (NHSi)-phosphine-based hybrid bidentate ligands [PhC(NtBu)2SiN(PR2)(2,6-iPr2-C6H3)] and Pd(dba)2, which serves as an effective catalyst for C-N cross-coupling of a wide range of sterically bulky amines and optically active amines, which is challenging otherwise. Herein, we report a hybrid silylene-based bidentate ligand (SiNP)-Pd(0) catalytic system, which performs the C-N coupling of difficult substrates, e.g., sterically bulky amines and chiral amines.</p>
},
	issn = {1359-7345},
	doi = {10.1039/d4cc03108c},
	author = {Kaulage, Sandeep H. and Parvin, Nasrina and Khopade, Kishor V. and Khan, Shabana}
}
