@article {49093,
	title = {Highly stereoselective diels-alder-based strategy for the synthesis of 3-epi-formicin A and 1-epi-formicin B},
	journal = {Organic Letters},
	volume = {26},
	year = {2024},
	month = {APR },
	pages = {3961-3965},
	type = {Article},
	abstract = {<p>
	The first enantioselective approach based on a highly stereoselective Diels-Alder reaction for the synthesis of 3-epi-formicin A and 1-epi-formicin B with rare N-acetylcysteamine-containing indenone thioesters is reported. The strategy utilizes a key Diels-Alder reaction to form the core hydrindane system with three contiguous stereocenters in very high levels of diastereo- and regioselectivity and one-pot oxidation/isomerization/dehydrogenation. The scope of this method was tested with different substrates to give cycloadducts in a highly diastereoselective manner.</p>
},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.4c01209},
	author = {Khamkar, Sunil L. and Handore, Kishor L. and Shinde, Harish M. and Reddy, D. Srinivasa}
}
