@article {48922,
	title = {Carbamate-Protected (BOC and O-NB) 2-Aminopyrimidinedione-based janus G-C nucleobase motifs as building blocks for supramolecular assembly and smart polymers},
	journal = {Journal of organic chemistry },
	volume = {88},
	year = {2023},
	month = {OCT },
	pages = {14953-14959},
	type = {Article},
	abstract = {<p>In this paper, we report {\textquoteleft}{\textquoteleft}carbamate protected{\textquoteright}{\textquoteright} 2-aminopyrimidinedione-based Janus G-C nucleobases (2-APD Janus G-C nucleobases) featuring polymerizable groups and self-complementary triple H-bonding motifs DDA and AAD as building blocks for developing smart polymers and self-healing materials. The carbamate-masked H-bonding motif, cleavable under acidic (BOC group) or photocleavable (O-nitrobenzyl group) conditions, would facilitate the synthesis of smart polymers by alleviating aggregation during polymerization which in turn would exclude self-assembly-assisted solubility issues. Ready accessibility in excellent yields coupled with the possibility for facile introduction of polymerizable groups would make these building blocks excellent candidates for diverse polymerization applications.</p>
},
	issn = {0022-3263},
	doi = {10.1021/acs.joc.3c01318},
	author = {Singh, Dharmendra and Lakshmi, Durga and Meena, Chhuttan L. and Krishna, Gamidi Rama and Sanjayan, Gangadhar J.}
}
