@article {48698,
	title = {Metal- and photocatalyst-free, visible-light-initiated C3 a-aminomethylation of quinoxalin-2(1H)-ones via electron donor-acceptor complexes},
	journal = {Journal of Organic Chemistry},
	volume = {88},
	year = {2023},
	month = {AUG },
	pages = {13339-13350},
	type = {Article},
	abstract = {<p>
	We report a metal- and photocatalyst-free C3 a-aminomethylation of quinoxalin-2(1H)-ones with N-alkyl-N-methylanilines. The reaction proceeds through the formation of a photoactivated electron donor-acceptor complex between quinoxalin-2(1H)-ones and N-alkyl-N-methylanilines. The present method provides a mild and environmentally friendly protocol that exhibits good atom economy and excellent functional group tolerance to obtain a library of biologically significant C3 a-aminomethylated quinoxalin-2(1H)-ones in good yields.</p>
},
	issn = {0022-3263},
	doi = {10.1021/acs.joc.3c01249},
	author = {More, Devidas A. and Shirsath, Sachin R. and Muthukrishnan, M.}
}
