@article {48690,
	title = {Zwitterionic disilanylium from an unsymmetrical disilene},
	journal = {Chemical Communications},
	volume = {59},
	year = {2023},
	month = {FEB },
	pages = {1669-1672},
	type = {Article},
	abstract = {<p>
	The reaction of PhC(NtBu)2SiSi(SiMe3)(3) (1) with Me3SiCH(2)Cl afforded an unsymmetrical sp(2)-sp(3) disilene, 2, with concomitant elimination of Me3SiCl. The analogous reaction with PhC(NtBu)2SiCl resulted in the oxidative addition of the C-Cl bond at the Si(II) atom (3). The reactions of 2 with sulfur and selenium led to compounds with Si=E (E=S (4) and Se (5)) double bonds. Tellurium reacted differently with 2 and furnished a zwitterionic compound, 6.</p>
},
	issn = {1359-7345},
	doi = {10.1039/d2cc06954g},
	author = {Bisai, Milan Kumar and Ajithkumar, V. S. and Raj, K. Vipin and Vanka, Kumar and Gonnade, Rajesh G. and Sen, Sakya S.}
}
