@article {47683,
	title = {Tuning of alpha-silyl carbocation reactivity into enone transposition: application to the synthesis of peribysin D, E-volkendousin, and E-guggulsterone},
	journal = {Organic Letters},
	volume = {23},
	year = {2021},
	month = {SEP },
	pages = {6642-6647},
	type = {Article},
	abstract = {A reliable method for enone transposition has been developed with the help of silyl group masking. Enantio-switching, substituent shuffling, and Z-selectivity are the highlights of the method. The developed method was applied for the first total synthesis of peribysin D along with its structural revision. Formal synthesis of E-guggulsterone and E-volkendousin was also claimed using a short sequence.},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.1c02173},
	author = {Athawale, Paresh R. and Zade, Vishal M. and Krishna, Gamidi Rama and Reddy, D. Srinivasa}
}
