@article {47082,
	title = {Bimetallic nano alloy architecture on a special polymer: Ni or Cu merged with Pd for the promotion of the Mizoroki-Heck reaction and the Suzuki-Miyaura coupling},
	journal = {Journal of Chemical Sciences},
	volume = {133},
	year = {2021},
	month = {FEB },
	pages = {8},
	type = {Article},
	abstract = {<p>Novel Ni-Pd and Cu-Pd bimetallic nano alloys was designed and heterogenized on the highly robust ABPBI [poly(2,5-benzimidazole)] polymer in high yields using NaBH4 as reducing agent. These were versatile ligand free catalysts for the Mizoroki-Heck reaction and Suzuki-Miyaura coupling. The bimetallic Ni-Pd-ABPBI catalyst for the Mizoroki-Heck reaction of 4-iodo anisole could be recycled 5 times with high yields. Aryl bromides could also be activated for the Mizoroki-Heck reaction using Cu-Pd-ABPBI NP catalysts, with moderate yields. Graphic abstractSynopsis Novel bimetallic Ni-Pd and Cu-Pd nano alloys, heterogenized on the robust ABPBI [poly(2,5-benzimidazole)] polymer using NaBH4 as reducing agent, is described. These were versatile ligand free, noble metal conservative catalysts, for the Mizoroki-Heck reaction and the Suzuki-Miyaura coupling. Aryl bromides were activated for the Mizoroki-Heck reaction using the Cu-Pd-ABPBI catalyst.</p>
},
	keywords = {Bimetallic nano alloys, Cu-Pd-ABPBI, Mizoroki-Heck reaction, Ni-Pd-ABPBI, Suzuki coupling},
	issn = {0974-3626},
	doi = {10.1007/s12039-020-01870-6},
	author = {Patil, Vijay P. and Kashid, Abhijit A. and Solanki, Bhanupratap S. and Kharul, Ulhas K. and Iyer, Suresh}
}
