@article {46680,
	title = {Access to diverse germylenes and a six-membered dialane with a flexible beta-diketiminate},
	journal = {Chemical Communications},
	volume = {56},
	year = {2020},
	month = {OCT},
	pages = {11871-11874},
	type = {Article},
	abstract = {<p>A nacnac-based tridentate ligand containing a picolyl group (L) was employed to isolate chlorogermylene (1). The reaction of1with another equivalent of GeCl2 center dot dioxane surprisingly gave pyridylpyrrolide-based chlorogermylene (2)viaC-N bond cleavage and C-C coupling, while with AlCl3, it afforded a transmetalated product,4. The reaction of L with AlH3 center dot NMe2Et led to an unusual cyclohexane type six-membered dialane heterocycle (5).</p>
},
	issn = {1359-7345},
	doi = {10.1039/d0cc05202g},
	author = {Pahar, Sanjukta and Swamy, V. S. V. S. N. and Das, Tamal and Gonnade, Rajesh G. and Vanka, Kumar and Sen, Sakya S.}
}
