@article {46607,
	title = {Radical rearrangement of aryl/alkylidene malononitriles via aza michael addition/decynoformylation/addition sequence: an access to alpha-aminonitriles and alpha-aminoamides},
	journal = {Journal of Organic Chemistry},
	volume = {85},
	year = {2020},
	month = {DEC },
	pages = {14858-14865},
	type = {Article},
	abstract = {<p>An efficient, safe, and environmentally friendly tertiary butyl hydrogen peroxide (TBHP)-mediated rearrangement of aryl/alkylidene malononitrile with anilines has been developed with in situ generation of HCN as the cyanide source for the synthesis of substituted alpha-aminonitriles and alpha-aminoamide. A diverse set of alpha-aminonitriles and alpha-aminoamides was efficiently synthesized in good to excellent yields. This method features a broad substrate scope and good functional group tolerance, and the in situ-generated HCN bypasses the use of an external cyanide source.</p>
},
	issn = {0022-3263},
	doi = {10.1021/acs.joc.0c01358},
	author = {Bhoite, Shubhangi P. and Bansodes, Ajay H. and Suryavanshi, Gurunath}
}
