@article {46337,
	title = {Allenoate prenucleophiles: a triply diastereoselective approach to beta-hydroxy esters containing all-carbon alpha-quaternary centers},
	journal = {Organic Letters},
	volume = {21},
	year = {2019},
	month = {OCT },
	pages = {7952-7955},
	type = {Article},
	abstract = {<p>Allenyl esters activated by titanium(IV) underwent additions to a wide range of aldehydes in high regio- and diastereoselectivities leading to products containing an all carbon quaternary center bearing an alpha-vinyl group that was installed with high selectivity for the Z-geometry. An aldol product was also converted to an indanone offering a new route to this important compound class. Product triple diastereoselectivity has been rationalized using a concerted transition-state model.</p>
},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.9b02930},
	author = {Maki, Samantha L. and Maity, Pradip and Dougherty, Shannon and Johns, Jennifer and Lepore, Salvatore D.}
}
